Peroxide, 1,1-dimethylpropyl 1-methoxycyclohexyl

Base Information

• Chemical Name: Peroxide, 1,1-dimethylpropyl 1-methoxycyclohexyl
• CAS No.: 125768-93-6
• Molecular Formula: C12H24O3
• Molecular Weight: 216.321
• Mol file: 125768-93-6.mol

Synonyms:

Chemical Property of Peroxide, 1,1-dimethylpropyl 1-methoxycyclohexyl

Chemical Property:

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Peroxide, 1,1-dimethylpropyl 1-methoxycyclohexyl

There total 2 articles about Peroxide, 1,1-dimethylpropyl 1-methoxycyclohexyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.1%

cycloxexanone dimethyl ketal (933-40-4) + tert-amyl hydroperoxide (3425-61-4) → 1-methoxy-1-t-amylperoxycyclohexane (125768-93-6)

Guidance literature:

With toluene-4-sulfonic acid; In dimethyl sulfoxide; at 20 ℃;

DOI:10.1021/jo00122a035

Reference yield:

methanol (67-56-1) + tert-amyl hydroperoxide (3425-61-4) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → 1,1-Bis(tert-pentylperoxy)cyclohexane (15667-10-4) + 1-methoxy-1-t-amylperoxycyclohexane (125768-93-6)

Guidance literature:

With sulfuric acid; at -6 - -4 ℃; for 0.25h;

Reference yield:

1-methoxy-1-t-amylperoxycyclohexane (125768-93-6) → tert-Amyl alcohol (75-85-4) + methyl hexanoate (106-70-7) + acetone (67-64-1) + 6-(1,1-Dimethyl-propoxy)-hexanoic acid methyl ester

Guidance literature:

With Isopropylbenzene; at 110 ℃; Rate constant; Thermodynamic data; ΔH(excit.), ΔS(excit.); other temp.;

DOI:10.1021/jo00122a035

upstream raw materials:

cycloxexanone dimethyl ketal

tert-amyl hydroperoxide

methanol

cyclohexanone

Downstream raw materials:

tert-Amyl alcohol

methyl hexanoate

acetone

Refernces

• 1、 Matsuyama, Kazuo,Sugiura, Takashi,Minoshima, Yoshihiko. "Substituent Effects of Alkyl Groups on the Decomposition of tert-Alkyl Peroxides". . p. 5520 - 5525. Retrieved 2007/10/02.