Dimethyl [(furan-2-yl)methyl]phosphonate

Base Information

Chemical Name:Dimethyl [(furan-2-yl)methyl]phosphonate
CAS No.:132112-90-4
Molecular Formula:C7H11O4P
Molecular Weight:190.136
Hs Code.:
DSSTox Substance ID:DTXSID90563199
Nikkaji Number:J346.710D
Wikidata:Q82447573

Synonyms:132112-90-4;DTXSID90563199;Dimethyl [(furan-2-yl)methyl]phosphonate

Suppliers and Price of Dimethyl [(furan-2-yl)methyl]phosphonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Dimethyl [(furan-2-yl)methyl]phosphonate

Chemical Property:

XLogP3:0.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:190.03949583
Heavy Atom Count:12
Complexity:174

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COP(=O)(CC1=CC=CO1)OC

Technology Process of Dimethyl [(furan-2-yl)methyl]phosphonate

There total 2 articles about Dimethyl [(furan-2-yl)methyl]phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 617-88-9
2-Chloromethylfuran

: 67-56-1
methanol

: 96-36-6,868-85-9
methyl phosphite

: 132112-90-4
furfuryl-phosphonic acid dimethyl ester

: 13679-46-4
2-(methoxymethyl)furan

Guidance literature:: With sodium methylate; In benzene; Product distribution; other halomethylfurans and phosphites, var. metalating agents;

Reference yield:

: 617-88-9
2-Chloromethylfuran

: 96-36-6,868-85-9
methyl phosphite

: 132112-90-4
furfuryl-phosphonic acid dimethyl ester

Guidance literature:: With sodium t-butanolate; Yield given. Multistep reaction; 1.) benzene, 65 deg C, 20 min, 2.) benzene, reflux, 30 min;

Reference yield:

: 132112-90-4
furfuryl-phosphonic acid dimethyl ester

: [(E)-Ethen-1,2-diyl]bis[(furan-5,2-diyl)methylen]bis[triphenylphosphonium]-dibromid

Guidance literature:: Multi-step reaction with 4 steps

1: 88 percent / K(t-BuO) / toluene / 1.) 60 deg C, 1 h; 2.) reflux, 6 h

2: 76 percent / POCl₃ / 1.) -30 deg C, 45 min; 2.) RT, 1 h; 3.) 80 deg C, 5 min

3: 99 percent / 2N NaOH, NaBH₄ / ethanol; tetrahydrofuran / 3 h / Ambient temperature

4: 62 percent / dimethylformamide / 1.)0 deg C, 30 min; 2.) RT, 3 d

With sodium hydroxide; sodium tetrahydroborate; potassium tert-butylate; trichlorophosphate; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide; toluene;