Methyl 3-(1,3-benzodioxol-5-yl)acrylate

Base Information

Chemical Name:Methyl 3-(1,3-benzodioxol-5-yl)acrylate
CAS No.:16386-34-8
Molecular Formula:C11H10O4
Molecular Weight:206.198
Hs Code.:
DSSTox Substance ID:DTXSID70353111
Wikidata:Q82130564,Q105310085
Mol file:16386-34-8.mol

Synonyms:Methyl 3-(1,3-benzodioxol-5-yl)acrylate;methyl 3-(1,3-benzodioxol-5-yl)prop-2-enoate;16386-34-8;Bionet2_001119;DTXSID70353111;WPNYKVVEDMUXTO-UHFFFAOYSA-N;AKOS017259808;FT-0772429;3-benzo[1,3]dioxol-5-yl-acrylic acid methyl ester

Suppliers and Price of Methyl 3-(1,3-benzodioxol-5-yl)acrylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Methyl3-(benzo[d][1,3]dioxol-5-yl)acrylate 97%
5g
$ 1786.00

Crysdot
Methyl3-(benzo[d][1,3]dioxol-5-yl)acrylate 97%
1g
$ 594.00

Atlantic Research Chemicals
Methyl3-(2H-1,3-Benzodioxol-5-yl)prop-2-enoate 95%
100mgs:
$ 120.18

Total 5 raw suppliers

Chemical Property of Methyl 3-(1,3-benzodioxol-5-yl)acrylate

Chemical Property:

PSA：44.76000
LogP:1.60150
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:206.05790880
Heavy Atom Count:15
Complexity:261

Purity/Quality:

99%, ^*data from raw suppliers

Methyl3-(benzo[d][1,3]dioxol-5-yl)acrylate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C=CC1=CC2=C(C=C1)OCO2

Technology Process of Methyl 3-(1,3-benzodioxol-5-yl)acrylate

There total 7 articles about Methyl 3-(1,3-benzodioxol-5-yl)acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.6%

: 120-57-0,30024-74-9
piperonal

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 16386-34-8
methyl 3-(3,4-dioxymethylenephenyl)propenoate

Guidance literature:: In tetrahydrofuran; at 0 - 20 ℃; for 24h;
DOI:10.1016/j.tet.2011.10.089

Reference yield: 66.0%

: 67-56-1
methanol

: 94-59-7
1-allyl-3,4-methylenedioxybenzene

: 16386-34-8
methyl 3-(3,4-dioxymethylenephenyl)propenoate

Guidance literature:: 1-allyl-3,4-methylenedioxybenzene; With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; for 0.416667h; Heating; Microwave irradiation;

methanol; With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; for 0.5h; Heating; Microwave irradiation;
DOI:10.1039/c1ob05293d

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 5927-18-4
trimethyl phosphonoacetate

: 16386-34-8
methyl 3-(3,4-dioxymethylenephenyl)propenoate

Guidance literature:: trimethyl phosphonoacetate; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;

piperonal; In tetrahydrofuran; for 2h; Inert atmosphere;
DOI:10.1016/j.tet.2020.131821