Methyl 2,3-dihydro-1,4-benzodioxine-6-carboxylate

Base Information

Chemical Name:Methyl 2,3-dihydro-1,4-benzodioxine-6-carboxylate
CAS No.:20197-75-5
Molecular Formula:C₁₀H₁₀O₄
Molecular Weight:194.187
Hs Code.:2932999099
DSSTox Substance ID:DTXSID20396639
Nikkaji Number:J1.491.465J
Wikidata:Q72464531
ChEMBL ID:CHEMBL2435587
Mol file:20197-75-5.mol

Synonyms:20197-75-5;Methyl 1,4-Benzodioxan-6-carboxylate;methyl 2,3-dihydro-1,4-benzodioxine-6-carboxylate;methyl 2,3-dihydrobenzo[b][1,4]dioxine-6-carboxylate;2,3-dihydro-1,4-benzodioxin-6-carboxylic acid methyl ester;1,4-Benzodioxin-6-carboxylic acid, 2,3-dihydro-, methyl ester;MFCD01544907;Methyl1,4-Benzodioxan-6-carboxylate;SCHEMBL668237;CHEMBL2435587;DTXSID20396639;GYUXWAIDEGEMEE-UHFFFAOYSA-N;2,3-DIHYDRO-1,4-BENZODIOXINE-6-CARBOXYLIC ACID METHYL ESTER;STL253530;AKOS000348972;AS-31621;SY014619;3,4-ethylenedioxybenzoic acid methyl ester;CS-0061853;FT-0660864;1,4-Benzodioxan-6-carboxylic acid methyl ester;EN300-7361788;A814322;J-521889;methyl 2,3-dihydrobenzo[1,4]dioxine-6-carboxylate;Z18922447;methyl 2,3-dihydrobenzo[b][1,4]-dioxine-6-carboxylate;2,3-dihydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester

Suppliers and Price of Methyl 2,3-dihydro-1,4-benzodioxine-6-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl1,4-Benzodioxan-6-carboxylate
50mg
$ 45.00

SynQuest Laboratories
2,3-Dihydro-1,4-benzodioxin-6-carboxylicacidmethylester 98%
5 g
$ 384.00

SynQuest Laboratories
2,3-Dihydro-1,4-benzodioxin-6-carboxylicacidmethylester 98%
25 g
$ 976.00

SynQuest Laboratories
2,3-Dihydro-1,4-benzodioxin-6-carboxylicacidmethylester 98%
1 g
$ 176.00

ChemScene
Methyl2,3-dihydro-1,4-benzodioxine-6-carboxylate 99.51%
10g
$ 268.00

ChemScene
Methyl2,3-dihydro-1,4-benzodioxine-6-carboxylate 99.51%
5g
$ 170.00

ChemScene
Methyl2,3-dihydro-1,4-benzodioxine-6-carboxylate 99.51%
25g
$ 448.00

ChemScene
Methyl2,3-dihydro-1,4-benzodioxine-6-carboxylate 99.51%
1g
$ 60.00

Chemenu
Methyl2,3-dihydrobenzo[b][1,4]dioxine-6-carboxylate 97%
25g
$ 437.00

Apolloscientific
2,3-Dihydro-1,4-benzodioxin-6-carboxylicacidmethylester 98%
25g
$ 610.00

Total 17 raw suppliers

Chemical Property of Methyl 2,3-dihydro-1,4-benzodioxine-6-carboxylate

Chemical Property:

Vapor Pressure:0.00183mmHg at 25°C
Refractive Index:1.537
Boiling Point:292.5°C at 760 mmHg
Flash Point:127.7°C
PSA：44.76000
Density:1.242g/cm³
LogP:1.24440
Storage Temp.:Inert atmosphere,Room Temperature
XLogP3:0.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:194.05790880
Heavy Atom Count:14
Complexity:216

Purity/Quality:

97% ^*data from raw suppliers

Methyl1,4-Benzodioxan-6-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC2=C(C=C1)OCCO2

Technology Process of Methyl 2,3-dihydro-1,4-benzodioxine-6-carboxylate

There total 13 articles about Methyl 2,3-dihydro-1,4-benzodioxine-6-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.26%

: 67-56-1
methanol

: 4442-54-0
2,3-dihydro-1,4-benzodioxin-6-carboxylic acid

: 20197-75-5
2,3-dihydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester

Guidance literature:: With sulfuric acid; at 70 ℃; for 5h;

Reference yield: 94.1%

: 2150-43-8
3,4-dihydroxybenzoic acid methyl ester

: 106-93-4
ethylene dibromide

: 20197-75-5
2,3-dihydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 90 ℃;

Reference yield: 69.0%

: 54110-86-0
2-(2-bromo-4-carboxylic acid methyl ester phenoxy)ethanol

: 20197-75-5
2,3-dihydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester

Guidance literature:: With 9-(2-di-tert-butylphosphanylphenyl)phenanthrene; palladium diacetate; caesium carbonate; In toluene; at 50 ℃; for 40h;
DOI:10.1021/ja012046d