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Ethyl difluoro(trimethylsilyl)acetate

Base Information Edit
  • Chemical Name:Ethyl difluoro(trimethylsilyl)acetate
  • CAS No.:205865-67-4
  • Molecular Formula:C7H14F2O2Si
  • Molecular Weight:196.269
  • Hs Code.:2915390090
  • European Community (EC) Number:801-542-8
  • DSSTox Substance ID:DTXSID10374562
  • Nikkaji Number:J1.236.297H
  • Wikidata:Q82163176
  • Mol file:205865-67-4.mol
Ethyl difluoro(trimethylsilyl)acetate

Synonyms:205865-67-4;ETHYL DIFLUORO(TRIMETHYLSILYL)ACETATE;Ethyl trimethylsilyldifluoroacetate;ethyl 2,2-difluoro-2-(trimethylsilyl)acetate;ethyl 2,2-difluoro-2-trimethylsilylacetate;Ethyl(trimethylsilyl)difluoroacetate;MFCD04973092;2,2-difluoro-2-(trimethylsilyl)acetic acid ethyl ester;C7H14F2O2Si;SCHEMBL8055619;AMY6906;DTXSID10374562;BBL101711;STL555508;AKOS006295443;FS-5715;SY063716;Trimethylsilyldifluoroacetic acid ethyl ester;E1314;ethyl2,2-difluoro-2-(trimethylsilyl)acetate;difluorotrimethylsilanylacetic acid ethyl ester;Ethyl 2,2-difluoro-2-(trimethylsilanyl)acetate;F12531

Suppliers and Price of Ethyl difluoro(trimethylsilyl)acetate
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • Ethyl 2,2-Difluoro-2-(trimethylsilyl)acetate
  • 1g
  • $ 235.00
  • TCI Chemical
  • Ethyl 2,2-Difluoro-2-(trimethylsilyl)acetate >97.0%(GC)
  • 1g
  • $ 112.00
  • TCI Chemical
  • Ethyl 2,2-Difluoro-2-(trimethylsilyl)acetate >97.0%(GC)
  • 5g
  • $ 337.00
  • SynQuest Laboratories
  • Ethyl difluoro(trimethylsilyl)acetate 95%
  • 5 g
  • $ 395.00
  • SynQuest Laboratories
  • Ethyl difluoro(trimethylsilyl)acetate 95%
  • 250 mg
  • $ 75.00
  • SynQuest Laboratories
  • Ethyl difluoro(trimethylsilyl)acetate 95%
  • 1 g
  • $ 145.00
  • Oakwood
  • Ethyltrimethylsilyldifluoroacetate 97%
  • 25g
  • $ 1495.00
  • Oakwood
  • Ethyl trimethylsilyldifluoroacetate
  • 1g
  • $ 142.00
  • Oakwood
  • Ethyl trimethylsilyldifluoroacetate
  • 250mg
  • $ 71.00
  • Oakwood
  • Ethyl trimethylsilyldifluoroacetate
  • 5g
  • $ 390.00
Total 15 raw suppliers
Chemical Property of Ethyl difluoro(trimethylsilyl)acetate Edit
Chemical Property:
  • Refractive Index:1.3930 to 1.3970 
  • Boiling Point:55°C/20mmHg(lit.) 
  • PSA:26.30000 
  • Density:1.010±0.06 g/cm3(Predicted) 
  • LogP:2.48210 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:4
  • Rotatable Bond Count:4
  • Exact Mass:196.07311254
  • Heavy Atom Count:12
  • Complexity:175
Purity/Quality:

98%,99%, *data from raw suppliers

Ethyl 2,2-Difluoro-2-(trimethylsilyl)acetate *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes: 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:CCOC(=O)C(F)(F)[Si](C)(C)C
  • Uses Ethyl 2,2-difluoro-2-(trimethylsilyl)acetate is a reagent for organic difluoromethylation and difluoromethylenation reactions.
Technology Process of Ethyl difluoro(trimethylsilyl)acetate

There total 10 articles about Ethyl difluoro(trimethylsilyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With inox; tetrabutylammomium bromide; aluminium; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at 20 ℃; Electrochemical reaction;
DOI:10.1016/S0040-4039(00)01509-4
Guidance literature:
With magnesium; In N,N-dimethyl-formamide; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol202289z
Guidance literature:
chloro-trimethyl-silane; With magnesium; copper(l) chloride; lithium chloride; In N,N-dimethylimidazolidinone; at 25 ℃; for 0.25h; Inert atmosphere;
ethyl trifluoroacetate,; In N,N-dimethylimidazolidinone; at 25 ℃; for 4h; Inert atmosphere;
With hydrogenchloride; In ethanol; at 25 ℃; for 1.5h; Inert atmosphere;
DOI:10.1016/j.tet.2011.10.109
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