(S)-4-[(R)-1,5-Dimethyl-3-oxohexyl]-1-cyclohexene-1-carboxylic acid methyl ester

Base Information

Chemical Name:(S)-4-[(R)-1,5-Dimethyl-3-oxohexyl]-1-cyclohexene-1-carboxylic acid methyl ester
CAS No.:26462-74-8
Molecular Formula:C16H26O3
Molecular Weight:266.37600
Hs Code.:
Mol file:26462-74-8.mol

Synonyms:(S)-4-((R)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarboxylic acid methyl ester;

Suppliers and Price of (S)-4-[(R)-1,5-Dimethyl-3-oxohexyl]-1-cyclohexene-1-carboxylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-4-[(R)-1,5-Dimethyl-3-oxohexyl]-1-cyclohexene-1-carboxylic acid methyl ester

Chemical Property:

PSA：43.37000
LogP:3.52730

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of (S)-4-[(R)-1,5-Dimethyl-3-oxohexyl]-1-cyclohexene-1-carboxylic acid methyl ester

There total 31 articles about (S)-4-[(R)-1,5-Dimethyl-3-oxohexyl]-1-cyclohexene-1-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-56-1
methanol

: 26462-78-2,26666-85-3,42719-55-1,51619-87-5,51619-88-6
(R)-4-(1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

: 16981-74-1,17015-46-2,17904-27-7,19908-46-4,26462-72-6,26462-74-8,26575-87-1,82079-49-0,82079-50-3,120019-21-8
Juvabion

Guidance literature:: With manganese(IV) oxide; sodium cyanide; acetic acid; Ambient temperature;
DOI:10.1016/S0040-4039(00)91276-0

Reference yield:

: 930-68-7
cyclohexenone

: 16981-74-1,17015-46-2,17904-27-7,19908-46-4,26462-72-6,26462-74-8,26575-87-1,82079-49-0,82079-50-3,120019-21-8
(+/-)-erythro-juvabione

Guidance literature:: Multi-step reaction with 8 steps

1: TiCl₄ / CH₂Cl₂ / -78 degC, 6 h, then -40 degC, 4 h

2: NaH / tetrahydrofuran

3: NaBH₄ / propan-2-ol

4: Et₃N / CH₂Cl₂

5: NaOMe / CH₂Cl₂

6: 1) (C₆H₁₁)2BH, 2) CrO₃ - H₂SO₄ / 1) THF, 2) Et₂O

7: (COCl)2 / benzene

8: Fe(acac)2 / tetrahydrofuran

With chromium(VI) oxide; sodium tetrahydroborate; oxalyl dichloride; iron(II) acetylacetonate; sulfuric acid; bis(cyclohexanyl)borane; sodium methylate; titanium tetrachloride; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane; isopropyl alcohol; benzene;
DOI:10.1016/S0040-4039(00)95158-X

Reference yield:

: 26462-80-6
(4S,8S)-p-menth-1-en-9-yl 3,5-dinitrobenzoate

: 26462-74-8
(-)-Juvabion

Guidance literature:: Multi-step reaction with 5 steps

1: (hydrolysis)

2: Py

4: (i), (ii) aq. H₂SO₄

With pyridine;
DOI:10.1021/ja00705a641