Methanesulfonimidoyl chloride, N-[(4-methylphenyl)sulfonyl]-

Base Information

• Chemical Name: Methanesulfonimidoyl chloride, N-[(4-methylphenyl)sulfonyl]-
• CAS No.: 28614-56-4
• Molecular Formula: C8H10ClNO3S2
• Molecular Weight: 267.757
• Mol file: 28614-56-4.mol

Synonyms:

Chemical Property of Methanesulfonimidoyl chloride, N-[(4-methylphenyl)sulfonyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methanesulfonimidoyl chloride, N-[(4-methylphenyl)sulfonyl]-

There total 6 articles about Methanesulfonimidoyl chloride, N-[(4-methylphenyl)sulfonyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

methylsulphinyl chloride (676-85-7) + chloroamine-T (127-65-1) → N-<(4-methylphenyl)sulfonyl>methanesulfonimidoyl chloride (28614-56-4)

Guidance literature:

In toluene; at 80 ℃; for 2h;

Reference yield:

N,N-dichloro-p-toluenesulfonamide (473-34-7) + methylsulphinyl chloride (676-85-7) → N-<(4-methylphenyl)sulfonyl>methanesulfonimidoyl chloride (28614-56-4)

Guidance literature:

With sulfuryl dichloride; Dimethyldisulphide; In chloroform; at 0 - 20 ℃; for 16h;

Reference yield:

N-(p-tolylsulfonyl)methanesulfinamide (132792-39-3) → N-<(4-methylphenyl)sulfonyl>methanesulfonimidoyl chloride (28614-56-4)

Guidance literature:

With chlorine; In dichloromethane; at -50 ℃; for 1h;

DOI:10.1021/jo00253a007

upstream raw materials:

methylsulphinyl chloride

toluene-4-sulfonamide

N-(p-tolylsulfonyl)methanesulfinamide

chloramine T trihydrate

Downstream raw materials:

(N-methanesulfone)-N-(4-methylbenzene)sulfonimide

N-(p-Tolylsulfonyl)-methansulfonimidamid

N-(p-Tolylsulfonyl)chlormethansulfinamid

N-[(dimethylamino)methyloxido-λ⁶-sulfanylidene]-4-methylbenzenesulfonamide