Deuterium

Base Information

• Chemical Name: Deuterium
• CAS No.: 12184-84-8
• Molecular Formula: H₂
• Molecular Weight: 4
• European Community (EC) Number: 231-952-7
• UN Number: 1957
• UNII: AR09D82C7G
• DSSTox Substance ID: DTXSID2064810
• Wikidata: Q6419441
• Mol file: 12184-84-8.mol

Synonyms:Deuterium;Deuterons;Hydrogen 2;Hydrogen-2

Chemical Property of Deuterium

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000
• XLogP3: 0
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 4.0282035557
• Heavy Atom Count: 0
• Complexity: 0
• Transport DOT Label: Flammable Gas

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Elements, Nonmetallic
• Canonical SMILES: [HH]
• Isomeric SMILES: [2H][2H]
• Recent ClinicalTrials: Pharmacokinetics Of Celecoxib Test Formulations

Technology Process of Deuterium

There total 237 articles about Deuterium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

iron(1,3-butadiene)(1+) (777920-07-7,102307-52-8) + acetylene-d2 (1070-74-2) → hydrogen (1333-74-0) + deuterium hydride + deuterium (16873-17-9,12184-84-8)

Guidance literature:

react. in MS-Fourier transform spectrometer under Ar;

DOI:10.1021/ja00047a060

Reference yield: 90.0%

niobocene trihydride (11105-67-2) + benzene-d6 (1076-43-3) → hydrogen (1333-74-0) + deuterium hydride + deuterium (16873-17-9,12184-84-8)

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); irradn. with 450-W Hanovia lamp for 36 h at 15°C (Ar); not isolated, detected by MS;

DOI:10.1021/ja00385a015

Reference yield: 84.0%

[1.1]ferrocenophane + deuterium cation → {Fe(C5(2)H4)2CH2}2 + hydrogen (1333-74-0) + deuterium hydride + deuterium (16873-17-9,12184-84-8)

Guidance literature:

In further solvent(s); React. of Fn in 3-methylsulfolane (3MS) with deuteriated acid mixt.; Quenching of react. (liq. N2), periodical removal of evolved H2, quenching in aq. soln. of SnCl2, extn. of reduced Fn (Et2O) and evapn. of Et2O.; Kinetics;

DOI:10.1021/om00095a008

upstream raw materials:

water

methane

water-d2

sodium

Downstream raw materials:

deuterium D2, ortho

deuterium sulfide

deuterium

carbon monoxide⁽¹⁺⁾

Refernces

• 1、 Zudin, V. N.,Rogov, V. A.,Likholobov, V. A.,Shmachkov, V. A.,Sazonov, L. A.,Ermakov, Yu. I.. "". . . Retrieved 1985.
• 2、 Czekay, Gregor,Drewello, Thomas,Schwarz, Helmut. "Oxidative Addition of the Carbon-Hydrogen Bond Is Not the Rate-Determining Step in the Remote Functionalization of Nitriles by Bare Fe(I) Ions". . p. 4561 - 4563. Retrieved 1989.
• 3、 Fultz,Witham,Udovic. "Distributions of hydrogen and strains in LaNi5 and LaNi4.75Sn0.25". . p. 165 - 175. Retrieved 2002.
• 4、 Ohno, Masayuki,Uzawa, Hisaji,Miyazaki, Teruhisa,Tarama, Kimio. "The Mechanism of the Photocatalytic Dehydrogenation of Methanol". . p. 779 - 782. Retrieved 1987.
• 5、 Kato, Chika Nozaki,Hara, Kazunobu,Hatano, Ayumi,Goto, Kazuhiro,Kuribayashi, Tomonori,Hayashi, Kunihiko,Shinohara, Akira,Kataoka, Yusuke,Mori, Wasuke,Nomiya, Kenji. "A Dawson-type dirhenium(V)-oxido-bridged polyoxotungstate: X-ray crystal structure and hydrogen evolution from water vapor under visible light irradiation". . p. 3134 - 3141. Retrieved 2008.
• 6、 Kleinberg,Jacobson,Silbernagel,Halbert. "NMR STUDIES ON HxTaS2 AND DxTaS2.". . p. 1541 - 1546. Retrieved 1980.
• 7、 Gao, Yanhong,Lin, Huaxiang,Zhang, Shiying,Li, Zhaohui. "Co(dmgH)2pyCl as a noble-metal-free co-catalyst for highly efficient photocatalytic hydrogen evolution over hexagonal ZnIn2S4". . p. 6072 - 6076. Retrieved 2016.
• 8、 Fisher, J. R.,Michael, J. V.. "Rate Constants for Reactions D * D2O -> D2 * OD by the Flash Photolysis-Shock Tube Technique over the Temperature Range 1285 - 2261 K: Results for the Back-Reaction and a Comparison to the Protonated Case". . p. 2465 - 2471. Retrieved 1990.
• 9、 Elliot, A. John,Chenier, Monique P.,Ouellette, Denis C.. "Temperature Dependence of g Values for H2O and D2O irradiated with Low Linear Energy Transfer Radiation". . p. 1193 - 1198. Retrieved 1993.
• 10、 Michaile, Sherie,Hillman, Manny,Eisch, John J.. "Kinetic study of the formation of dihydrogen from the reaction of [1.1]ferrocenophanes with strong acids. 2. Tensiometry, spectrometry, and deuterium exchange studies". . p. 1059 - 1065. Retrieved 1988.