1-Methoxybicyclo[4.1.0]heptane

Base Information

• Chemical Name: 1-Methoxybicyclo[4.1.0]heptane
• CAS No.: 34737-44-5
• Molecular Formula: C₈H₁₄O
• Molecular Weight: 126.199
• DSSTox Substance ID: DTXSID90548128
• Mol file: 34737-44-5.mol

Synonyms:1-Methoxybicyclo[4.1.0]heptane;methoxynorcarane;34737-44-5;SCHEMBL23829718;DTXSID90548128

Chemical Property of 1-Methoxybicyclo[4.1.0]heptane

Chemical Property:

• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 126.104465066
• Heavy Atom Count: 9
• Complexity: 122

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC12CCCCC1C2

Technology Process of 1-Methoxybicyclo[4.1.0]heptane

There total 1 articles about 1-Methoxybicyclo[4.1.0]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diiodomethane (75-11-6) + 1-methoxy-cyclohex-1-ene (931-57-7) → 2-methoxymethylenecyclohexane (10300-04-6) + 1-Methoxy-norcaran (34737-44-5)

Guidance literature:

With copper(l) chloride; zinc; In diethyl ether; for 40h; Yield given. Yields of byproduct given; Heating; in conc. solution;

DOI:10.1016/0022-328X(87)80300-5

Reference yield:

1-Methoxy-norcaran (34737-44-5) → 1,1-dimethoxy-2-methylcyclohexane (38574-09-3) + 1,1-dimethoxycycloheptane (25632-02-4) + 1-methoxycycloheptene (50438-50-1)

Guidance literature:

With (1,1'-biphenyl)-4,4'-dicarbonitrile; In methanol; Irradiation;

DOI:10.1021/jo00258a044

Reference yield:

methanol (67-56-1) + 1-Methoxy-norcaran (34737-44-5) → 1,1-dimethoxy-2-methylcyclohexane (38574-09-3) + 1,1-dimethoxycycloheptane (25632-02-4) + 1-methoxycycloheptene (50438-50-1)

Guidance literature:

With (1,1'-biphenyl)-4,4'-dicarbonitrile; Irradiation;

DOI:10.1021/jo00258a044

upstream raw materials:

diiodomethane

1-methoxy-cyclohex-1-ene

Downstream raw materials:

1,1-dimethoxy-2-methylcyclohexane

1,1-dimethoxycycloheptane

1-methoxycycloheptene