Oxadigermirane, tetrakis(2,4,6-trimethylphenyl)-

Base Information

• Chemical Name: Oxadigermirane, tetrakis(2,4,6-trimethylphenyl)-
• CAS No.: 400717-03-5
• Molecular Formula: C36H44Ge2O
• Mol file: 400717-03-5.mol

Synonyms:

Chemical Property of Oxadigermirane, tetrakis(2,4,6-trimethylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Oxadigermirane, tetrakis(2,4,6-trimethylphenyl)-

There total 2 articles about Oxadigermirane, tetrakis(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

triethylsilane (617-86-7) + hexamesitylcyclotrigermane (107824-84-0) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → 2,2,4,4-tetramesityl-1,3,2,4-dioxadigermetane (132775-06-5) + 2,2,4,4,5,5-hexamesityl-2,4,5-trigermadioxolane (400717-04-6) + tetramesityldigermadioxirane (400717-03-5) + (triethylsiloxydimesetyl)germanol (400717-05-7)

Guidance literature:

In toluene; Irradiation (UV/VIS); (Ar); dissolving of Et3SiH and Ge3(C6H2Me3)6 in toluene, irradn. (350 nm) at -70°C for 18 h; addn. via cannula of soln. m-chloroperbenzoic acid in dried degassed toluene; washing with satd. Na2SO3 and then with water, removal of solvent under vac., sepn. by chromy. (90/10 CH2Cl2-hexane);

DOI:10.1016/S0022-328X(01)01040-3

Reference yield: 14.0%

triethylsilane (617-86-7) + hexamesitylcyclotrigermane (107824-84-0) + oxygen (80937-33-3) → 2,2,4,4-tetramesityl-1,3,2,4-dioxadigermetane (132775-06-5) + 2,2,4,4,5,5-hexamesityl-2,4,5-trigermadioxolane (400717-04-6) + dimesityl(triethylsilyl)germane (144435-57-4) + tetramesityldigermadioxirane (400717-03-5) + 3,3,4,4-tetramesityl-3,4-digermadioxetane (400717-02-4)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); dissolving of Et3SiH and Ge3(C6H2Me3)6 in THF, irradn. (350 nm) at -70°C for 16 h under the ambient atmosphere; removal of solvent under vac., addn. of C6D6; crystn., filtration, sepn.by chromy. (CH2Cl2);

DOI:10.1016/S0022-328X(01)01040-3

upstream raw materials:

triethylsilane

hexamesitylcyclotrigermane

oxygen

3-chloro-benzenecarboperoxoic acid