Benzophenone phenylhydrazone

Base Information

• Chemical Name: Benzophenone phenylhydrazone
• CAS No.: 574-61-8
• Molecular Formula: C19H16N2
• Molecular Weight: 272.349
• Hs Code.: 2928000090
• European Community (EC) Number: 684-372-5
• NSC Number: 401195
• DSSTox Substance ID: DTXSID90972888
• Nikkaji Number: J95.760G
• Mol file: 574-61-8.mol

Synonyms:Benzophenone phenylhydrazone;574-61-8;Benzophenone, phenylhydrazone;N'-(Benzhydrylidene)-N-phenylhydrazine;N-(benzhydrylideneamino)aniline;Methanone, diphenyl-, phenylhydrazone;BRN 2215869;AI3-30023;1-(diphenylmethylidene)-2-phenylhydrazine;4-15-00-00069 (Beilstein Handbook Reference);Benzophenonphenylhydrazon;Methanone, phenylhydrazone;Benzophenone phenyl hydrazone;Diphenyl-methyl-diazo-benzene;SCHEMBL934433;DTXSID90972888;Diphenylmethanone phenylhydrazone #;MFCD00046773;NSC401195;AKOS003609078;NSC 401195;NSC-401195;1-(diphenylmethylene)-2-phenylhydrazine;AS-59549;LS-38949;A923153

Chemical Property of Benzophenone phenylhydrazone

Chemical Property:

• Vapor Pressure: 3.2E-07mmHg at 25°C
• Refractive Index: 1.8676 (estimate)
• Boiling Point: 418.7°Cat760mmHg
• Flash Point: 207°C
• PSA: 24.39000
• Density: 1.03g/cm³
• LogP: 4.62410
• Solubility.: Chloroform, DCM
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 272.131348519
• Heavy Atom Count: 21
• Complexity: 299

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=NNC2=CC=CC=C2)C3=CC=CC=C3
• Uses: N''-(Benzhydrylidene)-N-phenylhydrazine is an aryl hydrazine used in the preparation of various dyes and pharmaceutical compounds.

Technology Process of Benzophenone phenylhydrazone

There total 38 articles about Benzophenone phenylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bromobenzene (108-86-1,52753-63-6) + benzophenone hydrazone (5350-57-2) → benzophenone N-phenylhydrazone (574-61-8)

Guidance literature:

With sodium hydroxide; 2-(dicyclohexylphosphino)-2'-methylbiphenyl; palladium diacetate; In tert-Amyl alcohol; at 103 ℃; for 4h;

DOI:10.1002/adsc.200404392

Reference yield: 90.0%

benzophenone hydrazone (5350-57-2) + triphenylbismuth(V) diacetate (28899-97-0,7239-60-3) → benzophenone N-phenylhydrazone (574-61-8)

Guidance literature:

copper; In dichloromethane; for 24h; Ambient temperature;

DOI:10.1016/S0040-4039(00)84863-7

Reference yield: 87.0%

benzophenone (119-61-9) + phenylhydrazine (100-63-0) → benzophenone N-phenylhydrazone (574-61-8)

Guidance literature:

With Dowex resin acid form; In ethanol; for 0.916667h;

DOI:10.1080/00397910500184651

upstream raw materials:

diethyl ether

acetic acid-(benzylidene-phenyl-hydrazide)

2,8-Dioxa-3,4,6,7-tetraaza-3,6-nonadiene 4,6-dioxide

1-benzhydrylidene-5-phenyl carbonohydrazide

Downstream raw materials:

benzophenone

N-(diphenylmethylidene)phenylamine

1,1,2,2-tetraphenylethane

1,1-Diphenylmethanol