RHENIUM CARBONYL

Base Information

• Chemical Name: RHENIUM CARBONYL
• CAS No.: 14285-68-8
• Molecular Formula: C10O10 Re2
• Molecular Weight: 652.518
• Hs Code.: 2931 90 00
• NSC Number: 158174
• Mol file: 14285-68-8.mol

Synonyms:Rhenium carbonyl(Re2(CO)10) (6CI); Rhenium, decacarbonyldi- (8CI); Decacarbonyldirhenium;Decacarbonyldirhenium(0); Dirhenium decacarbonyl; NSC 158174;Pentacarbonylrhenium dimer

Chemical Property of RHENIUM CARBONYL

Chemical Property:

• Appearance/Colour: white to pale yellow crystalline solid
• Vapor Pressure: 0.000936mmHg at 25°C
• Melting Point: 170 °C (dec.)(lit.)
• Boiling Point: 303.3°Cat760mmHg
• Flash Point: 130.7°C
• PSA: 0.00000
• Density: g/cm³
• LogP: -2.08000
• Storage Temp.: Store below +30°C.
• Water Solubility.: soluble in most organic solvents [KIR82]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 0
• Exact Mass: 651.85786
• Heavy Atom Count: 22
• Complexity: 243

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dirhenium decacarbonyl ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Re].[Re]
• Uses: Decacarbonyldirhenium is a key starting material used for the synthesis of other rhenium carbonyl complexes. It plays an important role in metathesis, reforming and hydrogenation reactions. It is used as a catalyst to promote silation of alcohols and in the preparion of silyl ethers.

Technology Process of RHENIUM CARBONYL

There total 178 articles about RHENIUM CARBONYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

potassium hexachlororhenate(IV) + carbon monoxide (201230-82-2) → rhenium(I) pentacarbonyl chloride (14099-01-5) + decacarbonyldirhenium(0) (14285-68-8)

Guidance literature:

With sodium; In tetrahydrofuran; byproducts: KCl, NaCl; slight stoich. excess of Na, 1100 psi CO, 280°C, 40 h; cooling to room temp., filtration (celite), washing (THF), evapn., extn.into hexane, filtration, (Al2O3), evapn.;

DOI:10.1016/S0022-328X(97)00466-X

Reference yield: 74.0%

Li[cis-Re2(CO)9(CHO)]*tetrahydrofuran + benzaldehyde (100-52-7) → decacarbonyldirhenium(0) (14285-68-8) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With tetradecane; In tetrahydrofuran; under N2, 1.13 equiv of benzaldehyde in THF was added to soln. of Re-complex in THF, stirred for 1 h, water was added , extd. with ether, driedover Na2SO4, 1 equiv of tetradecane standard was added; solvent removed, dissolved in min. ether, hexane added, placed in freezer overnight, crystd., filtered, vac. dried;

Reference yield: 40.0%

pentacarbonylrhenium(1-) (14971-38-1,35725-77-0) + {(pentacarbonyl)rhenium(μ-η1:η2-vinyl)rhenium(pentacarbonyl)}BF4={(Pentacarbonyl)rhenium(μ-η1:η2-vinyl)rhenium(pentacarbonyl)}BF4 → sodium tetrafluoroborate (13755-29-8) + decacarbonyldirhenium(0) (14285-68-8) + (pentacarbonyl)rhenium(μ-ethanediyl)rhenium(pentacarbonyl)

Guidance literature:

In tetrahydrofuran; To a rhenium-complex in THF is added Re(CO)5(1-) under N2, under stirring the reaction mixture is warmed up to room temp.; sepn. of resulting ppt., removal of solvent, addn. of CH3OH to residue and stirring for 3 min, sepn. of a light yellow ppt., drying of ppt. under vac., sublimation to separate Re2(CO)10, elem. anal.;

DOI:10.1016/0022-328X(89)80120-2

upstream raw materials:

carbon monoxide

sodium perrhenate

Re₂(CO)9C₅H₄NCOC₆H₅

rheniumpentacarbonyl

Downstream raw materials:

rhenium(I) pentacarbonyl bromide

Re3(μ-H)2(μ3-S-2-EtC6H4)(μ-2,3,-dihydrobenzothiophene)(CO)9

rhenium(I) pentacarbonyl chloride

tris(2,2'-bipyridyl)cobalt(II)

Refernces

Rhenium carbonyl compounds with (diphenyl)phosphinoalkynes and a sterically hindered phosphinoalkyne

10.1016/j.jorganchem.2008.05.026

The research focuses on the synthesis and characterization of rhenium carbonyl complexes with P-coordinated phosphinoalkynes. The purpose of this study was to prepare new P-coordinated phosphinoalkynes with the fragment fac-{Re(CO)3}+, which would serve as starting materials to investigate the feasibility of a reaction similar to Scheme 1 with rhenium carbonyls, potentially leading to the formation of stable metallacycles in an aqueous medium. The researchers synthesized and characterized two series of rhenium carbonyl complexes, including anionic and neutral complexes with phosphinoalkynes, such as Ph2PC?CR (where R = Ph, Tol, tBu) and (o-Tol)2PC?CPh. The crystal structures of several complexes were determined using X-ray crystallography, and the electronic properties of the uncoordinated alkyne in these new rhenium complexes were analyzed based on 13C NMR data. The study concluded that the electronic characteristics of uncoordinated alkynes are similar in both rhenium and iron complexes, and the observed differences in reactivity between these metal complexes are related to the nature of the metallic fragments rather than the electronic features of the uncoordinated alkynes.