Silane, trimethyl(1-phenylethoxy)-, (S)-

Base Information

• Chemical Name: Silane, trimethyl(1-phenylethoxy)-, (S)-
• CAS No.: 42068-12-2
• Molecular Formula: C11H18OSi
• Molecular Weight: 194.349
• Mol file: 42068-12-2.mol

Synonyms:

Chemical Property of Silane, trimethyl(1-phenylethoxy)-, (S)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silane, trimethyl(1-phenylethoxy)-, (S)-

There total 9 articles about Silane, trimethyl(1-phenylethoxy)-, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1-Phenylethanol (98-85-1,13323-81-4) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → (S)-1-phenyl-1-trimethylsilyloxyethane (42068-12-2)

Guidance literature:

With 15,16-dibenzyl-12,15,16,19-tetrahydrodinaphtho-[2′,1′:2,3;1″,2′′:4,5][1,6]dioxacyclododecino[8,9-d:10,11-d′]bis-([1,2,3]triazole); In dichloromethane; at 20 ℃; for 12h; Resolution of racemate;

DOI:10.1039/c4ra09589h

Reference yield: 86.0%

Triethoxysilane (998-30-1) + acetophenone (98-86-2) → (R)-(+)-1-trimethylsiloxyethylbenzene (98857-41-1) + (S)-1-phenyl-1-trimethylsilyloxyethane (42068-12-2)

Guidance literature:

With [((4S,4S)-Ph-BOX)ZnOMe](at)SBA-15_-700; In [D₃]acetonitrile; at 60 ℃; for 5h; Reagent/catalyst; Inert atmosphere; Glovebox;

DOI:10.1021/acs.organomet.5b00714

Reference yield: 60.0%

1-phenyl-1-trimethylsilyloxyethane (14856-75-8) → 1-Phenylethanol (98-85-1,13323-81-4) + (S)-1-phenyl-1-trimethylsilyloxyethane (42068-12-2)

Guidance literature:

With potassium fluoride; C₄₆H₃₄I₄O₆; In 1,4-dioxane; at 20 ℃; for 144h; optical yield given as %ee; enantioselective reaction;

DOI:10.1002/anie.201004777

upstream raw materials:

1-phenyl-1-trimethylsilyloxyethane

1-styrenyloxytrimethylsilane

acetophenone

1-Phenylethanol

Downstream raw materials:

(S)-1-phenylethanol

[(S)-1-(1-Allyl-undec-10-enyloxy)-ethyl]-benzene

(R)-6-phenyl-4-<(S)-1-phenylmethoxy>-1-hexene

C₂₀H₂₄O