Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-

Base Information

• Chemical Name: Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-
• CAS No.: 4280-60-8
• Molecular Formula: C24H34O2
• Molecular Weight: 354.533
• Mol file: 4280-60-8.mol

Synonyms:

Chemical Property of Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-

There total 14 articles about Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-(para-anisyl)-5-bromopentane (14469-84-2) → 1,10-bis(4-methoxyphenyl)decane (4280-60-8)

Guidance literature:

With 2,2':6,2''-terpyridine; nickel(II) chloride hexahydrate; zinc; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;

DOI:10.1021/jacs.6b07733

Reference yield: 82.0%

1-bromo-4-methoxy-benzene (104-92-7) + 1,10-dibromodecane (4101-68-2) → 1,10-bis(4-methoxyphenyl)decane (4280-60-8)

Guidance literature:

1-bromo-4-methoxy-benzene; With iodine; magnesium; In tetrahydrofuran; for 12h; Reflux;

1,10-dibromodecane; With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(I) bromide; In tetrahydrofuran; for 24h; Reflux;

DOI:10.1139/v2012-014

Reference yield: 60.0%

1,10-dibromodecane (4101-68-2) + 4-methoxyphenyl magnesium bromide (13139-86-1) → 4,4'-Dimethoxybiphenyl (2132-80-1) + 1,10-bis(4-methoxyphenyl)decane (4280-60-8)

Guidance literature:

With dilithium tetrachlorocuprate; In tetrahydrofuran; for 12h; Ambient temperature;

upstream raw materials:

1-(para-anisyl)-5-bromopentane

4-methoxy-benzaldehyde

1,10-dibromodecane

4-methoxyphenyl magnesium bromide

Downstream raw materials:

1,10-bis(3-formyl-4-methoxyphenyl)decane

4,4'-decanediyl-di-phenol