1,3-Dimethylimidazolium iodide

Base Information

• Chemical Name: 1,3-Dimethylimidazolium iodide
• CAS No.: 4333-62-4
• Molecular Formula: C5H9IN2
• Molecular Weight: 224.044
• Hs Code.: 29332900
• European Community (EC) Number: 801-371-9
• NSC Number: 114468
• DSSTox Substance ID: DTXSID40962991
• Wikidata: Q27131032
• Metabolomics Workbench ID: 61590
• ChEMBL ID: CHEMBL1214173
• Mol file: 4333-62-4.mol

Synonyms:1,3-Dimethylimidazolium iodide;4333-62-4;1,3-dimethyl-1H-imidazol-3-ium iodide;1,3-dimethylimidazol-1-ium iodide;1-Methylimidazole methiodide;1,3-dimethylimidazol-1-ium;iodide;1,3-Dimethyl-3-imidazolium Iodide;NSC 114468;CHEBI:61324;MFCD00159685;IMIDAZOLIUM, 1,3-DIMETHYL-, IODIDE;1,3-Dimethylimidazoliumiodide;C5H9IN2;SCHEMBL359425;C5H9N2.I;1,3-dimethyl imidazolium iodide;CHEMBL1214173;DTXSID40962991;C5-H9-N2.I;NSC114468;AKOS015964830;1,3-dimethyl-1H-imidazol-3-iumiodide;NSC-114468;SB21851;AS-19711;LS-79775;SY039191;A6988;CS-0038445;D4654;FT-0600272;1H-Imidazolium, 1,3-dimethyl-, iodide (9CI);Q27131032

Chemical Property of 1,3-Dimethylimidazolium iodide

Chemical Property:

• Melting Point: 84.0 to 89.0 °C
• PSA: 8.81000
• LogP: -3.14640
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 223.98105
• Heavy Atom Count: 8
• Complexity: 55.1

Purity/Quality:

99% ^*data from raw suppliers

1,3-Dimethylimidazolium Iodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CN1C=C[N+](=C1)C.[I-]

Technology Process of 1,3-Dimethylimidazolium iodide

There total 28 articles about 1,3-Dimethylimidazolium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-methyl-1H-imidazole (616-47-7) + methyl iodide (74-88-4) → 1,3-dimethylimidazolim iodide (4333-62-4)

Guidance literature:

In dichloromethane; for 1h;

DOI:10.1021/acs.joc.5b01682

Reference yield: 100.0%

(1,3-dimethyl-1,3-dihydro-2H-imidazol-2-ylidene)diiodo(pyridine)palladium → 1,3-dimethylimidazolim iodide (4333-62-4)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; at 140 ℃; for 20h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.organomet.8b00124

Reference yield: 96.6%

2-(Hydroxy-diphenyl-methyl)-1,3-dimethyl-3H-imidazol-1-ium; iodide (111931-07-8) → benzophenone (119-61-9) + 1,3-dimethylimidazolim iodide (4333-62-4)

Guidance literature:

With potassium carbonate; In benzene; at 60 ℃; for 2h; Product distribution; further reagent; var. time;

upstream raw materials:

1H-imidazole

methyl iodide

1-methyl-1H-imidazole

2-(1-hydroxy-1-phenyl-1-pentyl)-1-methyl-1H-imidazole

Downstream raw materials:

1-methyl-1H-imidazole

methyl iodide

(2-chloro-5-methyl-4-pyrimidinyl)[3-(trifluoromethyl)phenyl]methanone

methylamine

Refernces

Selective synthesis of 1,4,5-trisubstituted imidazoles from α-imino ketones prepared by N-heterocyclic-carbene-catalyzed aroylation

10.1016/j.tet.2018.03.048

The study focuses on the selective synthesis of 1,4,5-trisubstituted imidazoles from α-imino ketones, which are prepared through N-heterocyclic-carbene (NHC)-catalyzed aroylation of imidoyl chlorides with aromatic aldehydes. The research outlines a straightforward methodology that involves NHC-catalyzed aroylation, followed by chemoselective reduction of the imino group, and subsequent annulation with formamide to form the imidazole ring. This approach allows the rapid and regioselective synthesis of imidazole derivatives with potential applications in pharmaceuticals and agrochemicals. The study demonstrates the substrate scope and optimization of reaction conditions, highlighting the importance of this method in creating chemical libraries for further application.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 4333-62-4 1,3-Dimethylimidazolium iodide

Send

Send

Metric Ton KG G Pound L ML

Send

Send