[difluoro(phenylsulfonyl)Methyl]triMethyl-Silane

Base Information

Chemical Name:[difluoro(phenylsulfonyl)Methyl]triMethyl-Silane
CAS No.:536975-50-5
Molecular Formula:C10H14F2O2SSi
Molecular Weight:264.368
Hs Code.:29350090
Mol file:536975-50-5.mol

Synonyms:trimethyl[difluoro(phenyl)methylsulfonyl]silane;[1-(Methoxy-methyl-carbamoyl)-ethyl]-carbamic acid tert-butyl ester;

Suppliers and Price of [difluoro(phenylsulfonyl)Methyl]triMethyl-Silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 10 raw suppliers

Chemical Property of [difluoro(phenylsulfonyl)Methyl]triMethyl-Silane

Chemical Property:

Boiling Point:96-97 °C(Press: 1 Torr)
PSA：42.52000
Density:1.162±0.06 g/cm3(Predicted)
LogP:4.43120

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of [difluoro(phenylsulfonyl)Methyl]triMethyl-Silane

There total 6 articles about [difluoro(phenylsulfonyl)Methyl]triMethyl-Silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 75-77-4
chloro-trimethyl-silane

: 80351-58-2
[(bromodifluoromethyl)sulfonyl]benzene

: 536975-50-5
[difluoro(phenylsulfonyl)methyl](trimethyl)silane

Guidance literature:: chloro-trimethyl-silane; [(bromodifluoromethyl)sulfonyl]benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 3.5h;

With hydrogenchloride; In tetrahydrofuran; hexane; Further stages.;
DOI:10.1016/j.tetlet.2008.01.034

Reference yield: 75.0%

: 536975-49-2
phenyl (trimethylsilyl)difluoromethyl sulfide

: 536975-50-5
[difluoro(phenylsulfonyl)methyl](trimethyl)silane

Guidance literature:: With ruthenium trichloride; sodium periodate; In tetrachloromethane; water; acetonitrile; at 0 - 25 ℃; for 2.5h; Cooling with ice;
DOI:10.1016/j.jfluchem.2017.07.001

Reference yield:

: 78031-08-0
[(bromodifluoromethyl)sulfanyl]benzene

: 536975-50-5
[difluoro(phenylsulfonyl)methyl](trimethyl)silane

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / Mg / dimethylformamide / 1 h / 20 °C

2: 51 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 0 - 20 °C

With magnesium; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo030110z