Technology Process of Cyclohexanone, 3,3-dimethyl-2-(2-propenyl)-
There total 12 articles about Cyclohexanone, 3,3-dimethyl-2-(2-propenyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
methyllithium;
With
copper(l) iodide;
In
diethyl ether;
at -25 ℃;
for 0.5h;
2-allyl-3-methyl-2-cyclohexen-1-one;
With
boron trifluoride diethyl etherate;
In
diethyl ether;
at -30 - -10 ℃;
DOI:10.1021/jo051082i
- Guidance literature:
-
methylmagnesium bromide;
With
copper(I) bromide dimethylsulfide complex;
In
tetrahydrofuran; diethyl ether;
at 0 ℃;
for 0.5h;
Inert atmosphere;
3-methylcyclohexen-2-one;
In
tetrahydrofuran; diethyl ether;
at 0 ℃;
for 0.583333h;
Inert atmosphere;
allyl bromide;
With
1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone;
In
tetrahydrofuran; diethyl ether;
at 0 - 20 ℃;
for 5.16667h;
Inert atmosphere;
DOI:10.1021/acs.orglett.9b02221
- Guidance literature:
-
3,3-dimethyl-1-<(trimethylsilyl)oxy>cyclohex-1-ene;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at 20 ℃;
for 2h;
Inert atmosphere;
allyl iodid;
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
In
tetrahydrofuran; hexane;
at -20 - 20 ℃;
DOI:10.1021/ol802375g
