cis-2-Decene

Base Information

• Chemical Name: cis-2-Decene
• CAS No.: 20063-97-2
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• Hs Code.: 2901299090
• European Community (EC) Number: 678-131-3
• NSC Number: 102790
• DSSTox Substance ID: DTXSID50891925
• Nikkaji Number: J82.954D
• Wikidata: Q76305242
• Mol file: 20063-97-2.mol

Synonyms:cis-2-Decene;20348-51-0;(Z)-dec-2-ene;(Z)-2-Decene;2-Decene, (Z)-;trans-2-Decene;(2Z)-2-Decene;(2Z)-2-Decene #;DTXSID50891925;YKNMBTZOEVIJCM-HYXAFXHYSA-N;MFCD00048946;NSC102790;(Z)-C10H20;NSC-102790;CS-0449480;D2161;T70533;J-013232

Chemical Property of cis-2-Decene

Chemical Property:

• Melting Point: -56.93°C (estimate)
• Refractive Index: 1.4206 (estimate)
• Boiling Point: 173.9°Cat760mmHg
• Flash Point: 46.9°C
• PSA: 0.00000
• Density: 0.749g/cm³
• LogP: 3.92300
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 140.156500638
• Heavy Atom Count: 10
• Complexity: 72.1

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCCCCC=CC
• Isomeric SMILES: CCCCCCC/C=C\C

Technology Process of cis-2-Decene

There total 86 articles about cis-2-Decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) → 5-decene (19689-19-1) + 4-decene (19689-18-0) + trans-3-decene (19150-21-1) + Decan-2-one (693-54-9) + 2-decene (20063-97-2,20348-51-0,6816-17-7)

Guidance literature:

With oxygen; 2,6-di-O-methyl-β-cyclodextrin; palladium(II) sulfate; H₉PV₆Mo₆O₄₀; copper(II) sulfate; In water; at 80 ℃; for 6h; under 750.06 Torr; Mechanism; Product distribution; influence of composition of catalytic mixture on selectivity of reaction;

Reference yield: 80.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) + Triethoxysilane (998-30-1) → 2-decene (20063-97-2,20348-51-0,6816-17-7) + 1-decyltriethoxysilane (2943-73-9)

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; In 5,5-dimethyl-1,3-cyclohexadiene; at 70 ℃; for 12h; Inert atmosphere;

DOI:10.1002/pola.28924

Reference yield: 73.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) → Decan-2-one (693-54-9) + 2-decene (20063-97-2,20348-51-0,6816-17-7)

Guidance literature:

With oxygen; cetyltrimethylammonim bromide; palladium dichloride; In water; benzene; at 80 ℃; for 48h; under 760 Torr; Product distribution; other phase transfer catalysts;

DOI:10.1016/S0040-4039(00)88385-9

upstream raw materials:

1-hexene

2-chloro-3-butene

1-Bromoheptane

1-bromo-1-propene

Downstream raw materials:

(Z)-2-decene

decane-2,3-dione

dec-3-en-2-one

2-decen-4-one

Refernces

• 1、 Sato,F. et al.. "-". . p. C30 - C32. Retrieved 1978.
• 2、 Satyanarayana, N.,Periasamy, M.. "ISOMERIZATION OF OLEFINS CATALYSED BY A CoCl2/Ph3P/NaBH4 SYSTEM". . p. 113 - 118. Retrieved 1987.
• 3、 Richel, Aurore,Delfosse, Sébastien,Cremasco, Cédric,Delaude, Lionel,Demonceau, Albert,Noels, Alfred F.. "Ruthenium catalysts bearing N-heterocyclic carbene ligands in atom transfer radical reactions". . p. 6011 - 6015. Retrieved 2003.
• 4、 Jones, Glen R.,Basbug Alhan, Hatice E.,Karas, Lucas J.,Wu, Judy I.,Harth, Eva. "Switching the Reactivity of Palladium Diimines with “Ancillary” Ligand to Select between Olefin Polymerization, Branching Regulation, or Olefin Isomerization". supporting information. p. 1635 - 1640. Retrieved 2020/11/30.
• 5、 Shin, Hyunseo,Moon, Bongjin. "Careful investigation of the hydrosilylation of olefins at poly(ethylene glycol) chain ends and development of a new silyl hydride to avoid side reactions". . p. 527 - 536. Retrieved 2018/01/27.