19150-21-1

Basic information

• Product Name: TRANS-3-DECENE
• Synonyms: (3E)-3-Decene;(E)-3-C10H20;(E)-3-decene;3-Decene, (E)-;trans-dec-3-ene;TRANS-3-DECENE
• CAS NO: 19150-21-1
• Molecular Formula: C₁₀H₂₀
• Molecular Weight: 140.27
• Mol File: 19150-21-1.mol
• Article Data: 25

Chemical Properties

• Melting Point: -56.93°C (estimate)
• Boiling Point: 166.82°C (estimate)
• Flash Point: 45.5°C
• Appearance: /
• Density: 0.7631 (estimate)
• Vapor Pressure: 2.08mmHg at 25°C
• Refractive Index: 1.4195 (estimate)
• CAS DataBase Reference: TRANS-3-DECENE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-3-DECENE(19150-21-1)
• EPA Substance Registry System: TRANS-3-DECENE(19150-21-1)

Safety Data

• Hazardous Substances Data: 19150-21-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 19, p. 191, 1978 DOI: 10.1016/S0040-4039(01)85081-4

InChI:InChI=1/C10H20/c1-3-5-7-9-10-8-6-4-2/h5,7H,3-4,6,8-10H2,1-2H3/b7-5+

Upstream product

• 98429-03-9 but-1-enyl-propyl ether 
• 3761-92-0 n-hexylmagnesium bromide 
• 22617-95-4 (E)-1-butenyl butyl ether 
• 111-71-7 heptanal 
• 74-85-1 ethene 
• 629-05-0 n-octyne 
• 872-05-9 1-Decene 
• 123-38-6 propionaldehyde 
• 91948-34-4 2-Methoxy-dec-3-yne 
• 70859-25-5 (3R*,4R*)-decane-3,4-diol 
• 79705-14-9 (3S,4R)-4-(tert-Butyl-dimethyl-silanyl)-decan-3-ol 
• 88726-55-0 1-[((E)-Dec-3-ene)-3-sulfonyl]-4-methyl-benzene 
• 74844-85-2 erythro-4-(trimethylsilyl)-3-decanol 
• 65949-99-7 Toluene-4-sulfonic acid 1-propyl-heptyl ester 

Downstream Products

• 53248-88-7 3,4-epoxydecane 
• 75-07-0 acetaldehyde 
• 123-72-8 butyraldehyde 
• 123-73-9 crotonaldehyde 

Relevant articles and documents

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Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel-N-Heterocyclic Carbene System

We report the catalytic addition of C-H bonds at the C2 position of heteroarenes, including pyrroles, indoles, benzofurans, and furans, to unactivated terminal and internal alkenes. The reaction is catalyzed by a combination of Ni(COD)2 and a sterically hindered, electron-rich N-heterocyclic carbene ligand or its analogous Ni(NHC)(arene) complex. The reaction is highly selective for anti-Markovnikov addition to α-olefins, as well as for the formation of linear alkylheteroarenes from internal alkenes. The reaction occurs with substrates containing ketones, esters, amides, boronate esters, silyl ethers, sulfonamides, acetals, and free amines.

Stabilization of long-chain intermediates in solution. octyl radicals and cations

The rearrangements of 1-octyl, 1-decyl and 1-tridecyl intermediates obtained from thermal lead(IV) acetate (LTA) decarboxylation of nonanoic, undecanoic and tetradecanoic acid were investigated experimentally through analysis and distribution of the products. The relationships between 1,5-, 1,6- and possibly existing 1,7-homolytic hydrogen transfer in 1-octyl-radical, as well as successive 1,2-hydride shift in corresponding cation have been computed via Monte-Carlo method. Taking into account that ratios of 1,5-/1,6-homolytic rearrangements in 1-octyl- and 1-tridecyl radical are approximately the same, the simulation shows very low involvement of 1,7-hydrogen rearrangement (1,5-/1,6-/1,7-hydrogen rearrangement = 85:31:1) in 1-octyl radical.