Ethylene glycol methacrylate phosphate

Base Information

• Chemical Name: Ethylene glycol methacrylate phosphate
• CAS No.: 35705-94-3
• Deprecated CAS: 103437-33-8,135623-25-5,145960-82-3,155275-64-2,176770-77-7,206277-89-6,73539-98-7,187820-79-7,135623-25-5,145960-82-3,155275-64-2,176770-77-7,187820-79-7,206277-89-6,73539-98-7
• Molecular Formula: C₁₄H₁₇O₆P
• Molecular Weight: 312.259
• European Community (EC) Number: 246-342-6,806-981-9
• UNII: QAA91B09KO
• DSSTox Substance ID: DTXSID70274211
• Nikkaji Number: J286.352I
• Wikidata: Q27287167
• ChEMBL ID: CHEMBL3186093
• Mol file: 35705-94-3.mol

Synonyms:EG-MCP cpd;ethylene glycol methacrylate phosphate

Chemical Property of Ethylene glycol methacrylate phosphate

Chemical Property:

• Boiling Point: 375.8°Cat760mmHg
• Flash Point: 181.1°C
• Density: 1.387g/cm³
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 210.02932506
• Heavy Atom Count: 13
• Complexity: 242

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCOP(=O)(O)O

Technology Process of Ethylene glycol methacrylate phosphate

There total 2 articles about Ethylene glycol methacrylate phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.6%

O-phenyl phosphorodichloridate (770-12-7) + allyl alcohol (107-18-6) + 2-hydroxyethyl acrylate (818-61-1,9051-31-4,26022-14-0) → C14H17O6P (35705-94-3)

Guidance literature:

O-phenyl phosphorodichloridate; allyl alcohol; With pyridine; In dichloromethane; at 0 ℃; for 8h; Inert atmosphere;

2-hydroxyethyl acrylate; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/pola.26845

Reference yield:

C9H10ClO3P + 2-hydroxyethyl acrylate (818-61-1,9051-31-4,26022-14-0) → C14H17O6P (35705-94-3)

Guidance literature:

With pyridine; at 20 ℃;

DOI:10.1016/j.reactfunctpolym.2013.06.011

Reference yield: 83.2%

rac-3-sulfanylpropane-1,2-diol (96-27-5) + C14H17O6P (35705-94-3) → C17H25O8PS

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1002/pola.26845

upstream raw materials:

O-phenyl phosphorodichloridate

allyl alcohol

2-hydroxyethyl acrylate

Refernces

• 1、 Ding, Liang,Lu, Rong,An, Jing,Zheng, Xueqin,Qiu, Jun. "Cyclic polyphosphoesters synthesized by acyclic diene metathesis polymerization and ring closing metathesis". . p. 1242 - 1248. Retrieved 2013.