Silane, (1,1-dimethylethyl)[[(1R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- 4-methylene-5-[(trimethylsilyl)oxy]cyclohexyl]oxy]diphenyl-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)[[(1R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- 4-methylene-5-[(trimethylsilyl)oxy]cyclohexyl]oxy]diphenyl-
CAS No.:633294-30-1
Molecular Formula:C32H52O3Si3
Molecular Weight:569.02
Hs Code.:

Silane,
(1,1-dimethylethyl)[[(1R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-
4-methylene-5-[(trimethylsilyl)oxy]cyclohexyl]oxy]diphenyl-

Synonyms:

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Chemical Property of Silane, (1,1-dimethylethyl)[[(1R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- 4-methylene-5-[(trimethylsilyl)oxy]cyclohexyl]oxy]diphenyl-

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Technology Process of Silane, (1,1-dimethylethyl)[[(1R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- 4-methylene-5-[(trimethylsilyl)oxy]cyclohexyl]oxy]diphenyl-

There total 6 articles about Silane, (1,1-dimethylethyl)[[(1R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- 4-methylene-5-[(trimethylsilyl)oxy]cyclohexyl]oxy]diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 75-77-4
chloro-trimethyl-silane

: 633294-26-5
(1S,3R,5R)-3-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-2-methylenecyclohexanol

: 633294-30-1
(1R,3S,5R)-1-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3-trimethylsilyloxy-2-methylenecyclohexane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 4h;
DOI:10.1055/s-2003-41025

Reference yield:

: 24120-79-4
(1R,2R,4S,6S)-(-)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-ol

: 633294-30-1
(1R,3S,5R)-1-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3-trimethylsilyloxy-2-methylenecyclohexane

Guidance literature:: Multi-step reaction with 5 steps

1.1: 91 percent / imidazole / toluene; dimethylformamide / 4 h / 20 °C

2.1: O₃ / methanol; CH₂Cl₂ / -78 °C

2.2: Ac₂O; Et₃N; DMAP / methanol; CH₂Cl₂ / 12 h / Heating

2.3: 68 percent / K₂CO₃ / methanol / 3 h / 20 °C

3.1: 88 percent / imidazole / dimethylformamide / 3 h / 20 °C

4.1: 89 percent / diethylaluminium N-cyclohexyl-N-iso-propylamide / benzene / 3 h / 20 °C

5.1: 100 percent / imidazole / dimethylformamide / 4 h / 20 °C

With 1H-imidazole; diethylaluminium N-cyclohexyl-N-iso-propylamide; ozone; In methanol; dichloromethane; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1055/s-2003-41025

Reference yield:

: 99-48-9,1197-06-4,1197-07-5,2102-58-1,2102-59-2,5157-78-8,5503-11-7,7632-16-8,18383-51-2,22567-18-6,20307-86-2
(4R,6R)-carveol

: 633294-30-1
(1R,3S,5R)-1-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-3-trimethylsilyloxy-2-methylenecyclohexane

Guidance literature:: Multi-step reaction with 6 steps

1.1: 81 percent / MCPBA / CH₂Cl₂

2.1: 91 percent / imidazole / toluene; dimethylformamide / 4 h / 20 °C

3.1: O₃ / methanol; CH₂Cl₂ / -78 °C

3.2: Ac₂O; Et₃N; DMAP / methanol; CH₂Cl₂ / 12 h / Heating

3.3: 68 percent / K₂CO₃ / methanol / 3 h / 20 °C

4.1: 88 percent / imidazole / dimethylformamide / 3 h / 20 °C

5.1: 89 percent / diethylaluminium N-cyclohexyl-N-iso-propylamide / benzene / 3 h / 20 °C

6.1: 100 percent / imidazole / dimethylformamide / 4 h / 20 °C

With 1H-imidazole; diethylaluminium N-cyclohexyl-N-iso-propylamide; ozone; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1055/s-2003-41025