5,5,6,6-Tetramethoxycyclohexa-1,3-diene

Base Information

• Chemical Name: 5,5,6,6-Tetramethoxycyclohexa-1,3-diene
• CAS No.: 65492-28-6
• Molecular Formula: C10H16O4
• Molecular Weight: 200.235
• DSSTox Substance ID: DTXSID00513721
• Wikidata: Q82373656
• Mol file: 65492-28-6.mol

Synonyms:5,5,6,6-Tetramethoxycyclohexa-1,3-diene;65492-28-6;tetramethoxycyclohexadiene;DTXSID00513721

Chemical Property of 5,5,6,6-Tetramethoxycyclohexa-1,3-diene

Chemical Property:

• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 200.10485899
• Heavy Atom Count: 14
• Complexity: 211

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: COC1(C=CC=CC1(OC)OC)OC

Technology Process of 5,5,6,6-Tetramethoxycyclohexa-1,3-diene

There total 1 articles about 5,5,6,6-Tetramethoxycyclohexa-1,3-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + 1,2-dimethoxybenzene (91-16-7) → o-benzoquinone bis(dimethyl acetal) (65492-28-6)

Guidance literature:

With potassium hydroxide; (electrolysis);

DOI:10.1021/ja00899a044

Reference yield: 84.0%

o-benzoquinone bis(dimethyl acetal) (65492-28-6) + lithium prop-2-en-1-amine → Allyl-(2,3-dimethoxy-phenyl)-amine

Guidance literature:

In diethyl ether; at 0 ℃; for 3h;

DOI:10.1039/c39820000878

Reference yield: 76.0%

o-benzoquinone bis(dimethyl acetal) (65492-28-6) + lithium diisopropyl amide (4111-54-0) → 5-(di-isopropylamino)-1,6,6-trimethoxy-1,3-cyclohexadiene

Guidance literature:

DOI:10.1039/c39820000878

upstream raw materials:

methanol

1,2-dimethoxybenzene

Downstream raw materials:

1,2-dimethoxy-4-butylbenzene

1-Butyl-2,3-dimethoxy-benzene

3-Isopropyl-veratrol

1-isopropyl 3,4-dimethoxy benzene