Iron,tricarbonylbis(trimethyl phosphite-P)- (9CI)

Base Information

• Chemical Name: Iron,tricarbonylbis(trimethyl phosphite-P)- (9CI)
• CAS No.: 14949-85-0
• Molecular Formula: C₉H₁₈FeO₉P₂
• Molecular Weight: 388.031
• Mol file: 14949-85-0.mol

Synonyms:Iron,tricarbonylbis(phosphorous acid)-, hexamethyl ester (8CI); Iron,tricarbonylbis(trimethyl phosphite)- (7CI)

Chemical Property of Iron,tricarbonylbis(trimethyl phosphite-P)- (9CI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Iron,tricarbonylbis(trimethyl phosphite-P)- (9CI)

There total 1 articles about Iron,tricarbonylbis(trimethyl phosphite-P)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

Fe(CO)3{Fe(CO)3CHC(C6H5)S} + phosphorous acid trimethyl ester (121-45-9) → tricarbonylbis(trimethylphosphite)iron (19457-84-2,14949-85-0) + Fe2(CO)5(P(OCH3)3)HCC(C6H5)(S)

Guidance literature:

With sodium amalgam; In diethyl ether; addn. of soln. from Fe complex and TMP (-30°C) to sodium amalgam in Schlenk tube; vigorously stirring under cooling, <10°C, 10 min;decantation; evapn.; dissoln. in n-pentane-toluene; chromy. (silica gel, -30°C, n-pentane:toluene 1:1); recrystn. from n-pentane, -30°C; elem. anal.;

DOI:10.1016/0022-328X(90)80068-B

Reference yield:

tricarbonylbis(trimethylphosphite)iron (19457-84-2,14949-85-0) → dicarbonylbis(trimethylphosphite)diphenyl-p-tolylketene imine iron (125979-20-6)

Guidance literature:

Multi-step reaction with 2 steps

1: nitrogen / diethyl ether

2: diethyl ether

With nitrogen; In diethyl ether;

DOI:10.1016/0022-328X(89)87232-8

Reference yield:

tricarbonylbis(trimethylphosphite)iron (19457-84-2,14949-85-0) → dicarbonylbis(trimethylphosphite)diphenylketene iron (125963-16-8,125994-63-0)

Guidance literature:

Multi-step reaction with 2 steps

1: nitrogen / diethyl ether

2: diethyl ether

With nitrogen; In diethyl ether;

DOI:10.1016/0022-328X(89)87232-8

upstream raw materials:

phosphorous acid trimethyl ester

Downstream raw materials:

dicarbonylbis(trimethylphosphite)diphenyl-p-tolylketene imine iron

dicarbonylbis(trimethylphosphite)diphenylketene iron