(3Z)-3-(phenylhydrazinylidene)piperidin-2-one

Base Information

Chemical Name:(3Z)-3-(phenylhydrazinylidene)piperidin-2-one
CAS No.:57073-81-1
Molecular Formula:C11H13N3O
Molecular Weight:203.244
Hs Code.:
NSC Number:225799,207283

Synonyms:(3Z)-3-(phenylhydrazinylidene)piperidin-2-one;Piperidine-2,3-dione, 3-phenylhydrazone;57073-81-1;NSC207283;YQCAVNMBDOXHCX-UVTDQMKNSA-N;HMS1667M19;NSC225799;CCG-247451;NSC-207283;NSC-225799;(3Z)-2,3-Piperidinedione 3-(phenylhydrazone) #

Suppliers and Price of (3Z)-3-(phenylhydrazinylidene)piperidin-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (3Z)-3-(phenylhydrazinylidene)piperidin-2-one

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:1.23g/cm³
XLogP3:1.6
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:203.105862047
Heavy Atom Count:15
Complexity:257

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC(=NNC2=CC=CC=C2)C(=O)NC1
Isomeric SMILES:C1C/C(=N/NC2=CC=CC=C2)/C(=O)NC1

Technology Process of (3Z)-3-(phenylhydrazinylidene)piperidin-2-one

There total 14 articles about (3Z)-3-(phenylhydrazinylidene)piperidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 41907-06-6
piperidinedione

: 100-63-0
phenylhydrazine

: 57073-81-1
3-(Phenylhydrazone) of 2,3-piperidinedione

Guidance literature:: In ethanol; dichloromethane; for 0.25h; Heating;

Reference yield:

: 19365-08-3,220928-01-8
3-hydroxypiperidin-2-one

: 57073-81-1
3-(Phenylhydrazone) of 2,3-piperidinedione

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) oxalyl chloride, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, 15 min, 2.) room temperature

2: 96 percent / ethanol; CH₂Cl₂ / 0.25 h / Heating

With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In ethanol; dichloromethane;

Reference yield:

: 17216-62-5
diethyl 2-(2-cyanoethyl)malonate

: 57073-81-1
3-(Phenylhydrazone) of 2,3-piperidinedione

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / Raney Ni / ethanol / 6 h / 80 °C / 58840.6 Torr

2: 1.) aq. KOH, 2.) aq. CH₃COOH / 1.) RT, overnight, 2.) 0 deg C, 4 h

With potassium hydroxide; hydrogen; acetic acid; nickel; In ethanol;
DOI:10.1021/jm00051a007