METHYL 5-BROMO-2-FUROATE

Base Information

• Chemical Name: METHYL 5-BROMO-2-FUROATE
• CAS No.: 2527-99-3
• Molecular Formula: C6H5BrO3
• Molecular Weight: 205.008
• Hs Code.: 29321900
• Mol file: 2527-99-3.mol

Synonyms:RARECHEM AL BF 0601;BUTTPARK 94\04-07;METHYL-2-BROMOFURAN-CARBOXYLATE;METHYL 5-BROMOFURAN-2-CARBOXYLATE;METHYL 5-BROMO-2-FUROATE;5-BROMO-2-FUROIC ACID METHYL ESTER;5-BROMO-FURAN-2-CARBOXYLIC ACID METHYL ESTER;AKOS BBS-00004656

Chemical Property of METHYL 5-BROMO-2-FUROATE

Chemical Property:

• Appearance/Colour: White to slightly yellow crystalline powder
• Vapor Pressure: 0.0824mmHg at 25°C
• Melting Point: 63-68 °C
• Refractive Index: 1.513
• Boiling Point: 226.314 °C at 760 mmHg
• Flash Point: 90.672 °C
• PSA: 39.44000
• Density: 1.623 g/cm³
• LogP: 1.82870
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Water Solubility.: Slightly soluble in water.

Purity/Quality:

99%, ^*data from raw suppliers

Methyl5-bromofuran-2-carboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: It is used in the preparation of hydroquinone bis(2-carbomethoxy-5-furyl ether).

Technology Process of METHYL 5-BROMO-2-FUROATE

There total 2 articles about METHYL 5-BROMO-2-FUROATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Z)-methyl 2-acetoxy-5-nitro-2,5-dihydro-2-furancarboxylate (57505-57-4) → 2-furoic acid methyl ester (611-13-2) + methyl 5-bromo-2-furoate (2527-99-3)

Guidance literature:

With hydrogen bromide; In dichloromethane; for 0.166667h; Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/jo00370a012

Reference yield:

2-furoic acid methyl ester (611-13-2) → 5-bromo-furan-2-carboxylic acid (585-70-6) + methyl 5-bromo-2-furoate (2527-99-3)

Guidance literature:

With bromine;

DOI:10.1021/jo01111a008

Reference yield: 98.3%

methanol (67-56-1) + methyl 5-bromo-2-furoate (2527-99-3) + carbon monoxide (201230-82-2) → furan-2,5-dicarboxylic acid dimethyl ester (4282-32-0)

Guidance literature:

With 1-methyl-1H-imidazole; palladium diacetate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; at 100 ℃; for 15h; under 4137.29 - 51716.2 Torr; Reagent/catalyst; Pressure; Temperature;

upstream raw materials:

2-furoic acid methyl ester

(Z)-methyl 2-acetoxy-5-nitro-2,5-dihydro-2-furancarboxylate

Downstream raw materials:

5-cyclohexyloxy-furan-2-carboxylic acid

5-carbamoyl-furan-2-carboxylic acid

trans-1,3-Bismethoxycarbonyl-3,3-dimethoxypropen

2,2-bis<4-<(2-carbomethoxy-5-furyl)oxy>phenyl>propane

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 2527-99-3 METHYL 5-BROMO-2-FUROATE

Send

Send

Metric Ton KG G Pound L ML

Send

Send