cis-Triamminetrichloroiridium (III)

Base Information

Chemical Name:cis-Triamminetrichloroiridium (III)
CAS No.:63976-47-6
Molecular Formula:Cl₃H₉IrN₃
Molecular Weight:349.671
Hs Code.:
DSSTox Substance ID:DTXSID50981390

Synonyms:cis-Triamminetrichloroiridium (III);IRIDIUM (III), TRIAMMINETRICHLORO-, cis-;63976-47-6;Cl3H9IrN3;Cl3-H9-Ir-N3;DTXSID50981390;LS-84197;Iridium(3+) chloride--ammonia (1/3/3);Iridium, triamminetrichloro-, (OC-6-22)-

Suppliers and Price of cis-Triamminetrichloroiridium (III)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of cis-Triamminetrichloroiridium (III)

Chemical Property:

Vapor Pressure:5990mmHg at 25°C
Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:348.94913
Heavy Atom Count:7
Complexity:0

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:N.N.N.[Cl-].[Cl-].[Cl-].[Ir+3]

Technology Process of cis-Triamminetrichloroiridium (III)

There total 5 articles about cis-Triamminetrichloroiridium (III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: IrCl₃*3.1H₂O

: 57-13-6
urea

: chloropentaammineiridium(III) chloride

: 25456-36-4,60183-09-7,63976-47-6
mer-Ir(NH3)3Cl3

: 113667-93-9,38504-25-5
trans-{Ir(NH₃)4Cl₂}Cl

: 113667-93-9,38504-25-5
cis-{Ir(NH₃)4Cl₂}Cl

Guidance literature:: With acetic acid; In water; refluxing of IrCl3*3.1H2O and acetic acid soln., urea addn., refluxing (5 h), cooling to room temp., evapn. (reduced pressure), heating (150°C, 12 h), filtration (Sephadex C-25), partial evapn., addn. of excess HCl, refluxing (2 h); filtration off of (Ir(NH3)5Cl)Cl2, evapn. to dryness, washing (EtOH), extn. (hot H2O), washing of residue (H2O), extn. (hot H2O); chromy. of joined H2O-extracts (Sephadex), crystn.; elem. anal.;

Reference yield: 13.0%

: IrCl₃*3.1H₂O

: 57-13-6
urea

: chloropentaammineiridium(III) chloride

: 25456-36-4,60183-09-7,63976-47-6
mer-Ir(NH3)3Cl3

: 113667-93-9,38504-25-5
trans-{Ir(NH₃)4Cl₂}Cl

: 113667-93-9,38504-25-5
cis-{Ir(NH₃)4Cl₂}Cl

: Ir(NH₃)5(OOCCH₃)⁽²⁺⁾*2Cl^(1-)={Ir(NH₃)5(OOCCH₃)}Cl₂

Guidance literature:: With acetic acid; In water; refluxing of IrCl3*3.1H2O and acetic acid soln., urea addn., refluxing (5 h), cooling to room temp., evapn. (reduced pressure), heating (150°C, 12 h), filtration (Sephadex C-25); further product; evapn., extn. (EtOH, H2O), chromy. of filtrate (Sephadex, elution with LiCl soln.), evapn., extn. (2 M-LiCl), evapn. of filtrate, extn. (EtOH), washing of residue (EtOH, Et2O), drying;