Bi-2,4-cyclopentadien-1-yl, 1,1',2,2',3,3',4,4',5,5'-decamethyl-

Base Information

• Chemical Name: Bi-2,4-cyclopentadien-1-yl, 1,1',2,2',3,3',4,4',5,5'-decamethyl-
• CAS No.: 69446-48-6
• Molecular Formula: C20H30
• Molecular Weight: 270.458
• Mol file: 69446-48-6.mol

Synonyms:

Chemical Property of Bi-2,4-cyclopentadien-1-yl, 1,1',2,2',3,3',4,4',5,5'-decamethyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bi-2,4-cyclopentadien-1-yl, 1,1',2,2',3,3',4,4',5,5'-decamethyl-

There total 13 articles about Bi-2,4-cyclopentadien-1-yl, 1,1',2,2',3,3',4,4',5,5'-decamethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

chloro-trimethyl-silane (75-77-4) + (1,2,3,4,5-pentamethylcyclopentadienide)UO2(2,6-((2,4,6-trimethylphenyl)N=CMe)2C5H3N) + Triphenylphosphine oxide (791-28-6) → 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine (210155-39-8) + decamethylfulvalene (69446-48-6) + (Me3SiO)2UCl2(OPPh3)2

Guidance literature:

(1,2,3,4,5-pentamethylcyclopentadienide)UO₂(2,6-((2,4,6-trimethylphenyl)N=CMe)2C₅H₃N); Triphenylphosphine oxide; In toluene; for 0.0833333h; Inert atmosphere; Schlenk technique; Glovebox;

chloro-trimethyl-silane; In toluene; for 4h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c5dt04776e

Reference yield: 82.0%

trimethylsilyl iodide (16029-98-4) + (1,2,3,4,5-pentamethylcyclopentadienide)UO2(2,6-((2,4,6-trimethylphenyl)N=CMe)2C5H3N) + Triphenylphosphine oxide (791-28-6) → 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine (210155-39-8) + decamethylfulvalene (69446-48-6) + (Me3SiO)2UI2(OPPh3)2

Guidance literature:

(1,2,3,4,5-pentamethylcyclopentadienide)UO₂(2,6-((2,4,6-trimethylphenyl)N=CMe)2C₅H₃N); Triphenylphosphine oxide; In toluene; for 0.0833333h; Inert atmosphere; Schlenk technique; Glovebox;

trimethylsilyl iodide; In toluene; for 4h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c5dt04776e

Reference yield: 79.0%

trimethylsilyl trifluoromethanesulfonate (27607-77-8) + (1,2,3,4,5-pentamethylcyclopentadienide)UO2(2,6-((2,4,6-trimethylphenyl)N=CMe)2C5H3N) + Triphenylphosphine oxide (791-28-6) → 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine (210155-39-8) + decamethylfulvalene (69446-48-6) + (Me3SiO)2U(OTf)2(OPPh3)2

Guidance literature:

(1,2,3,4,5-pentamethylcyclopentadienide)UO₂(2,6-((2,4,6-trimethylphenyl)N=CMe)2C₅H₃N); Triphenylphosphine oxide; In toluene; for 0.0833333h; Inert atmosphere; Schlenk technique; Glovebox;

trimethylsilyl trifluoromethanesulfonate; In toluene; for 4h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c5dt04776e

upstream raw materials:

Phenylselenyl chloride

indium chloride

lithium pentamethylcyclopentadienide

indium(III) chloride

Downstream raw materials:

1,2,3,4,5-pentamethylcyclopentadiene

1,2,3,4-tetramethylfulvene

Refernces

• 1、 Becker, Lisanne,Rei?, Fabian,Altenburger, Kai,Spannenberg, Anke,Arndt, Perdita,Jiao, Haijun,Rosenthal, Uwe. "Reactivity Study of Pyridyl-Substituted 1-Metalla-2,5-diaza-cyclopenta-2,4-dienes of Group 4 Metallocenes". supporting information. p. 10826 - 10838. Retrieved 2016/07/27.
• 2、 Beachley Jr.,Blom, Richard,Churchill, Melvyn Rowen,Faegri Jr., Knut,Fettinger, James C.,Pazik,Victoriano. "(Pentamethylcyclopentadienyl)indium(I) and -indium(III) compounds. Syntheses, reactivities, and X-ray diffraction and electron diffraction studies of In(C5Me5)". . p. 346 - 356. Retrieved 2008/10/08.