Iron(II) methoxide

Base Information

• Chemical Name: Iron(II) methoxide
• CAS No.: 7245-21-8
• Molecular Formula: 3CH₃O*Fe
• Molecular Weight: 148.95
• European Community (EC) Number: 677-749-0
• DSSTox Substance ID: DTXSID50562067
• Mol file: 7245-21-8.mol

Synonyms:Iron(II) methoxide;7245-21-8;Iron(2+) dimethoxide;iron(2+);methanolate;C-Oxazol-2-yl-methylamine;SCHEMBL284312;DTXSID50562067;AKOS025295663

Chemical Property of Iron(II) methoxide

Chemical Property:

• PSA: 18.46000
• LogP: 0.19170
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 117.971715
• Heavy Atom Count: 5
• Complexity: 2

Purity/Quality:

97% ^*data from raw suppliers

Iron(II)methoxide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[O-].C[O-].[Fe+2]
• Uses: Iron(II) methoxide, is used in Engineering & Environmental, Catalysis & Synthesis, and In organic syntheses, chemical research.

Technology Process of Iron(II) methoxide

There total 6 articles about Iron(II) methoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(III) chloride + sodium methylate (124-41-4) → iron(III) methoxide (7245-21-8,7245-25-2,92274-53-8)

Guidance literature:

In ethanol; toluene; for 8h; Inert atmosphere;

DOI:10.1039/c4dt03491k

Reference yield:

methanol (67-56-1) + (C2H5)2Fe(2,2'-bipyridyl)2 → Eisen(II)-methylat (7245-21-8,7245-25-2,92274-53-8)

Guidance literature:

In tetrahydrofuran; byproducts: C2H6; under N2, alcohol added to THF soln. of Fe complex at -78°C, react. vessel evacuated, mixt. allowed to react at room temp. for 1 d; concd., diethyl ether added, ppt. filtered, washed with hexane and diethyl ether a few times, dried in vac., elem. anal.;

DOI:10.1246/bcsj.53.673

Reference yield:

sodium methylate (124-41-4) + iron(II) (7439-89-6,15438-31-0) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → ferrocene (102-54-5,55404-68-7) + Eisen(II)-methylat (7245-21-8,7245-25-2,92274-53-8)

Guidance literature:

In not given; addn. of C5H6 to Fe(2+) halogenide at ambient temp. and presence of high excess of NaOCH3;;

upstream raw materials:

methanol

Fe₂(O^tBu)₆

sodium methylate

iron(II)