tris(2,2'-bipyridyl)-Fe(II) complex

Base Information

• Chemical Name: tris(2,2'-bipyridyl)-Fe(II) complex
• CAS No.: 15025-74-8
• Molecular Formula: C₃₀H₂₄FeN₆
• Molecular Weight: 524.408
• Mol file: 15025-74-8.mol

Synonyms:Iron(2+),tris(2,2'-bipyridine)-, ion (8CI); Iron(2+), tris(2,2'-bipyridine-N,N')-,(OC-6-11)-; Biperroin; Ferrodiin; Tris(2,2'-bipyridine)iron(2+);Tris(2,2'-bipyridine)iron(II); Tris(2,2'-bipyridine)iron(II) cation;Tris(2,2'-bipyridine)iron(II) hydrochloride; Tris(2,2'-bipyridyl)iron(2+);Tris(2,2'-bipyridyl)iron(II); Tris(2,2'-dipyridyl)iron(2+); Tris(bipyridine)iron(2+)

Chemical Property of tris(2,2'-bipyridyl)-Fe(II) complex

Chemical Property:

• Boiling Point: 272.5°Cat760mmHg
• Flash Point: 107.2°C
• PSA: 77.34000
• Density: g/cm³
• LogP: 6.42830

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tris(2,2'-bipyridyl)-Fe(II) complex

There total 19 articles about tris(2,2'-bipyridyl)-Fe(II) complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercury dichloride + potassium ferrocyanide → tris(2,2'-bipyridine)iron(II)(2+) (15025-74-8,55122-50-4,24162-11-6) + mercury(II) cyanide (592-04-1)

Guidance literature:

With [2,2]bipyridinyl; potassium nitrate; In water; byproducts: Cl(1-), CN(1-); K4(Fe(CN)6), 2,2'-bipyridine and KNO3 mixed quickly with excess of HgCl2 in water, at 292-302 K; detected by UV; Kinetics;

DOI:10.1016/0022-1902(81)80397-1

Reference yield:

Rh(CNC6H5)4(1+)*ClO4(1-)=[Rh(CNC6H5)4]ClO4 (83771-90-8) + tris(2,2'-bipyridine)iron(III) hexafluorophosphate → tris(2,2'-bipyridine)iron(II)(2+) (15025-74-8,55122-50-4,24162-11-6) + [Rh(C6H5NC)4](2+)

Guidance literature:

With n-Bu₄NClO₄; In acetonitrile; Rh- and Fe-complexes were mixed in MeCN contg. 0.1 mol/dm**3 n-Bu4NClO4at 298 K; monitored spectrophotometrically; Kinetics;

DOI:10.1246/bcsj.55.3482

Reference yield:

tris(2,2'-bipyridine)iron(III) ion (18661-69-3) + C28H44N4Rh(1+) (34178-82-0) → tris(2,2'-bipyridine)iron(II)(2+) (15025-74-8,55122-50-4,24162-11-6) + [Rh(C6H11NC)4](2+)

Guidance literature:

With tetrabutylammonium perchlorate; In acetonitrile; in MeCN contg. 0.1 M n-Bu4NClO4 at 298 K; Kinetics;

DOI:10.1246/bcsj.55.2892

upstream raw materials:

mercury⁽¹⁺⁾

dimercury⁽²⁺⁾

cobalt(II)

iron(III)

Downstream raw materials:

tris(2,2'-bipyridine)iron(III) ion

cis-nitrous acid

[2,2]bipyridinyl

iron(II)