Methyl 1-ethyl-2-methoxycyclohexa-2,5-diene-1-carboxylate

Base Information

Chemical Name:Methyl 1-ethyl-2-methoxycyclohexa-2,5-diene-1-carboxylate
CAS No.:82478-12-4
Molecular Formula:C11H16O3
Molecular Weight:196.246
Hs Code.:
DSSTox Substance ID:DTXSID30537177

Synonyms:82478-12-4;Methyl 1-ethyl-2-methoxycyclohexa-2,5-diene-1-carboxylate;DTXSID30537177

Suppliers and Price of Methyl 1-ethyl-2-methoxycyclohexa-2,5-diene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Methyl 1-ethyl-2-methoxycyclohexa-2,5-diene-1-carboxylate

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:196.109944368
Heavy Atom Count:14
Complexity:278

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC1(C=CCC=C1OC)C(=O)OC

Technology Process of Methyl 1-ethyl-2-methoxycyclohexa-2,5-diene-1-carboxylate

There total 3 articles about Methyl 1-ethyl-2-methoxycyclohexa-2,5-diene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 74-96-4
ethyl bromide

: 579-75-9
2-Methoxybenzoic acid

: 1,4-diethyl-cyclohexa-2,5-dienecarboxylic acid methyl ester

: 1,4-diethyl-2-methoxy-cyclohexa-2,5-dienecarboxylic acid methyl ester

: 606-45-1
2-methoxybenzoic acid methyl ester

: 82478-12-4
1-Ethyl-2-methoxy-cyclohexa-2,5-dienecarboxylic acid methyl ester

Guidance literature:: 2-Methoxybenzoic acid; With sodium; In ammonia;

ethyl bromide; In ammonia;

diazomethane; In diethyl ether;
DOI:10.1016/j.tetlet.2005.11.138

Reference yield:

: 606-45-1
2-methoxybenzoic acid methyl ester

: 82478-12-4
1-Ethyl-2-methoxy-cyclohexa-2,5-dienecarboxylic acid methyl ester

Guidance literature:: With ammonia; tert-butyl alcohol; Multistep reaction; 1) THF, -78 deg C, 2) -78 deg C;
DOI:10.1021/jo00197a020

Reference yield:

: 606-45-1
2-methoxybenzoic acid methyl ester

: 75-03-6
ethyl iodide

: 82478-12-4
1-Ethyl-2-methoxy-cyclohexa-2,5-dienecarboxylic acid methyl ester

Guidance literature:: With penta-1,3-diene; potassium tert-butylate; ammonia; potassium; Yield given. Multistep reaction; 1.) THF, t-butyl alcohol, -70 deg C 2.) THF;
DOI:10.1016/S0040-4039(00)87030-6