3-METHOXYPHENANTHRENE

Base Information

• Chemical Name: 3-METHOXYPHENANTHRENE
• CAS No.: 835-06-3
• Molecular Formula: C15H12O
• Molecular Weight: 208.26
• Hs Code.: 2909309090
• Mol file: 835-06-3.mol

Synonyms:3-Methoxy-phenanthren;Phenanthrene, 3-methoxy-;Phenanthrene,3-methoxy;3-methoxyphenantrene;

Chemical Property of 3-METHOXYPHENANTHRENE

Chemical Property:

• PSA: 9.23000
• LogP: 4.00160

Purity/Quality:

99% ^*data from raw suppliers

3-METHOXYPHENANTHRENE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-METHOXYPHENANTHRENE

There total 12 articles about 3-METHOXYPHENANTHRENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

4-(2-bromo-vinyl)-anisole (27570-08-7,60592-52-1,6303-59-9) + 2-(trimethylsilyl)phenyl trifluoromethanesulfonate (88284-48-4) → 3-methoxyphenanthrene (835-06-3)

Guidance literature:

With cesium fluoride; In acetonitrile; at 50 ℃; for 12h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.joc.9b01644

Reference yield: 84.0%

3'-methoxy-2-(2''-methoxyvinyl)-1,1'-biphenyl (1024598-29-5) → 1-methoxyphenanthrene (834-99-1) + 3-methoxyphenanthrene (835-06-3)

Guidance literature:

With mercuric triflate; In toluene; at 20 ℃; for 0.166667h;

DOI:10.1021/ol800450x

Reference yield: 10.0%

(Z)-1-chloro-2-(4-methoxystyryl)benzene → E-1-(phenyl)-2-(4'-methoxyphenyl)ethene (1694-19-5) + 3-methoxyphenanthrene (835-06-3)

Guidance literature:

With potassium; potassium iodide; magnesium chloride; In tetrahydrofuran; for 12h; Heating;

upstream raw materials:

methanol

E-1-(phenyl)-2-(4'-methoxyphenyl)ethene

2,2,2-trifluoroethanol

3'-methoxy-2-(2''-methoxyvinyl)-1,1'-biphenyl

Downstream raw materials:

1-(3-methoxy-9-phenanthrenyl)ethanone

(-)-(R)-3,3'-dihydroxy-4,4'-biphenanthrene