DIETHYLALUMINUM ETHOXIDE

Base Information

• Chemical Name: DIETHYLALUMINUM ETHOXIDE
• CAS No.: 1586-92-1
• Molecular Formula: C6H15 Al O
• Molecular Weight: 130.166
• Hs Code.: 2909199090
• Mol file: 1586-92-1.mol

Synonyms:(Ethanolato)diethylaluminum;Dealox; Diethylaluminium ethoxide; Diethylaluminum ethoxide; Diethylaluminummonoethoxide; Diethylethoxyaluminum; Ethoxydiethylaluminum

Chemical Property of DIETHYLALUMINUM ETHOXIDE

Chemical Property:

• Vapor Pressure: 5 mm Hg ( 94 °C)
• Melting Point: 2.5-4.5oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: g/cm³
• LogP: 2.43500
• Storage Temp.: 0-6°C
• Sensitive.: Air & Moisture Sensitive
• Solubility.: Soluble in hydrocarbons and ether.

Purity/Quality:

99.9% ^*data from raw suppliers

Diethylaluminum ethoxide 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): FC
• Hazard Codes: F,T,C
• Statements: 11-14-17-23/24/25-34-14/15-67-65-48/20-63
• Safety Statements: 16-26-36/37/39-45-43-27-62

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIETHYLALUMINUM ETHOXIDE

There total 6 articles about DIETHYLALUMINUM ETHOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triethylaluminum (97-93-8) + sodium ethanolate (141-52-6) → diethyl(ethoxy)aluminum (1586-92-1) + sodium tetraethylaluminate (2397-68-4)

Guidance literature:

In hexane; n-heptane; toluene; at 70 ℃; for 1h;

Reference yield:

triethylaluminum (97-93-8) + aluminum ethoxide (555-75-9) → diethyl(ethoxy)aluminum (1586-92-1)

Guidance literature:

Reference yield:

hexaethyldialuminum → diethyl(ethoxy)aluminum (1586-92-1)

Guidance literature:

With O₂; In xylene; shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};

DOI:10.1016/0022-328X(88)80228-6

upstream raw materials:

triethylaluminum

sodium ethanolate

aluminum ethoxide

Downstream raw materials:

(4S,5S)-4-Acetyl-5-phenyl-dihydro-furan-2-one

β-acetyl-γ-phenyl-γ-butyrolactone

2-ethoxy-5-methyltetrahydropyran

5-hexanolide

Refernces

• 1、 Dzhemilev, U. M.,Kukovinets, A. G.. "MECHANISM OF LINEAR OLIGOMERIZATION OF BUTADIENE, CATALYZRD BY LOW-VALENCE COMPLEXES OF COBALT AND IRON". . . Retrieved 1983.
• 2、 -. "Process for the preparation of alkali metal tetraalkylaluminates and use thereof". Page/Page column 2. . Retrieved 2008/06/13.