Stannane, dimethylbis[4-(trifluoromethyl)phenyl]-

Base Information

Chemical Name:Stannane, dimethylbis[4-(trifluoromethyl)phenyl]-
CAS No.:86393-09-1
Molecular Formula:C16H14F6Sn
Molecular Weight:438.988
Hs Code.:

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Chemical Property of Stannane, dimethylbis[4-(trifluoromethyl)phenyl]-

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Technology Process of Stannane, dimethylbis[4-(trifluoromethyl)phenyl]-

There total 1 articles about Stannane, dimethylbis[4-(trifluoromethyl)phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.4%

: 402-51-7
4-(trifluoromethyl)phenylmagnesium bromide

: 753-73-1
dimethyltin dichloride

: 86393-09-1
(methyl)2Sn(C₆H₄-p-OCF₃)2

Guidance literature:: In not given; N2; cooling a flask with aryl-Grignard reagent to -78°C, addn. ofsolid Sn compd. (0.5 equiv.), stirring at -78°C for 20 min, warm ing to room temp., stirring over several hs.; removal of volatiles under reduced pressure, addn. of hexanes, filtration (Celite), washing the solid with hexanes, concg. the combined organic soln.;
DOI:10.1021/ic034150x

Reference yield: 69.0%

: 86393-09-1
(methyl)2Sn(C₆H₄-p-OCF₃)2

: 86393-12-6
CF₃C₆H₄Sn(CH₃)2I

Guidance literature:: With iodine; In tetrachloromethane; 25°C; Davison, A.; Rakita, P. E. J. Organomet. Chem. 1970, 23, 407;;
DOI:10.1021/ja00355a025

Reference yield: 31.0%

: 86393-09-1
(methyl)2Sn(C₆H₄-p-OCF₃)2

: 10294-34-5
boron trichloride

: 591215-80-4
bis[4-(trifluoromethyl)phenyl]chloroborane

Guidance literature:: In n-heptane; byproducts: dimethyltin dichloride; glovebox; addn. of 1 equiv. of BCl3 as 1 M soln. in heptane to a flask contg. dimethyldiaryltin and heptane at room temp., sealing, stirring at room temp. for 30 min, heating at 100°C in oil bath for 24-48 h; cooling, decantation, removal of volatiles, recrystn. from petroleum ether at -35°C;
DOI:10.1021/ic034150x