(E)-1-Phenyl-1-butene

Base Information

• Chemical Name: (E)-1-Phenyl-1-butene
• CAS No.: 824-90-8
• Molecular Formula: C10H12
• Molecular Weight: 132.205
• European Community (EC) Number: 260-079-4
• DSSTox Substance ID: DTXSID301026549
• Nikkaji Number: J91.284K,J91.285I
• Wikidata: Q81988402
• Mol file: 824-90-8.mol

Synonyms:1-phenyl-1-butene;1-phenyl-1-butene, (trans)-isomer

Chemical Property of (E)-1-Phenyl-1-butene

Chemical Property:

• Melting Point: -43°C
• Refractive Index: 1.5330
• Boiling Point: 189.85°C
• PSA: 0.00000
• Density: 0.9059 (estimate)
• LogP: 3.10980
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 132.093900383
• Heavy Atom Count: 10
• Complexity: 96.6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=CC1=CC=CC=C1
• Isomeric SMILES: CC/C=C/C1=CC=CC=C1

Technology Process of (E)-1-Phenyl-1-butene

There total 106 articles about (E)-1-Phenyl-1-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

n-propyltriphenylphosphonium bromide (6228-47-3) + benzaldehyde (100-52-7) → 1-phenylbut-1-ene (824-90-8) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

With water; potassium carbonate; In 1,4-dioxane; at 95 ℃; for 1.25h;

DOI:10.1016/S0040-4020(01)87435-4

Reference yield:

cellulose (9004-34-6) → 1-phenylpropene (637-50-3) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + ethene (74-85-1) + o-xylene (95-47-6) + para-xylene (106-42-3) + 1-phenylbut-1-ene (824-90-8) + ethylbenzene (100-41-4,27536-89-6) + m-xylene (108-38-3,104809-90-7) + toluene (108-88-3,15644-74-3,16713-13-6) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

With ZSM-5 zeolite; at 550 ℃; Temperature;

DOI:10.1016/j.apcata.2014.05.015

Reference yield:

cyclopropyl phenyl ketone (3481-02-5) + phenylsilane (694-53-1) → 1-phenylbut-1-ene (824-90-8) + 1-phenyl-1-cyclopropylmethanol (1007-03-0) + C16H18OSi (1425941-73-6) + (PhCH(C3H5)O)2SiHPh (1425941-74-7,1454318-49-0,1454318-51-4) + propiophenone (495-40-9)

Guidance literature:

With [Ru^VI(N)(N,N’-bis(salicylidene)-o-cyclohexyldiamine dianion)(CH₃OH)][ClO₄]; In benzene-d6; Reflux;

DOI:10.1021/cs300848h

upstream raw materials:

1-butylbenzene

2-phenylbut-2-ene

4-phenyl-butan-1-ol

2-phenylbutan-1-ol

Downstream raw materials:

2-phenylthiophene

(rac)-(E)-2-acetoxy-4-phenylbut-3-ene

1-acetoxy-1-phenylbutan-2-ol

2-acetoxy-1-phenylbutan-1-ol