Methyl 2-bromo-5-methoxybenzoate

Base Information

Chemical Name:Methyl 2-bromo-5-methoxybenzoate
CAS No.:35450-36-3
Molecular Formula:C9H9BrO3
Molecular Weight:245.073
Hs Code.:29189900
European Community (EC) Number:609-129-2
DSSTox Substance ID:DTXSID80380271
Nikkaji Number:J340.473K
Wikidata:Q72488611
Mol file:35450-36-3.mol

Synonyms:Methyl 2-bromo-5-methoxybenzoate;35450-36-3;methyl-2-Bromo-5-Methoxybenzoate;2-Bromo-5-methoxybenzoic Acid Methyl Ester;Benzoic acid, 2-bromo-5-methoxy-, methyl ester;2-bromo-5-methoxy-benzoic acid methyl ester;MFCD00051594;METHYL2-BROMO-5-METHOXYBENZOATE;Methyl 6-Bromo-m-anisate;SCHEMBL385581;DTXSID80380271;methyl 2-bromo-5-methoxylbenzoate;methyl 2-bromo-5-methoxy benzoate;STR09008;6-Bromo-m-anisic Acid Methyl Ester;AKOS005254622;Methyl 2-bromo-5-methoxybenzoate, 97%;SY035501;methyl-2-bromo-5-methoxybenzene carboxylate;2-bromo-5-methoxybenzoic acid, methyl ester;CS-0080148;FT-0628437;M1934;A822816

Suppliers and Price of Methyl 2-bromo-5-methoxybenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl 2-Bromo-5-methoxybenzoate
10g
$ 85.00

TCI Chemical
Methyl 2-Bromo-5-methoxybenzoate >98.0%(GC)
25g
$ 120.00

TCI Chemical
Methyl 2-Bromo-5-methoxybenzoate >98.0%(GC)
5g
$ 34.00

SynQuest Laboratories
Methyl 2-bromo-5-methoxybenzoate
100 g
$ 400.00

SynQuest Laboratories
Methyl 2-bromo-5-methoxybenzoate
25 g
$ 136.00

SynQuest Laboratories
Methyl 2-bromo-5-methoxybenzoate
5 g
$ 39.00

Sigma-Aldrich
Methyl 2-bromo-5-methoxybenzoate 97%
25g
$ 265.00

Sigma-Aldrich
Methyl 2-bromo-5-methoxybenzoate 97%
5g
$ 69.90

Matrix Scientific
Methyl 2-Bromo-5-methoxybenzoate >95%
100g
$ 892.00

Frontier Specialty Chemicals
Methyl 2-Bromo-5-methoxybenzoate 98%
5g
$ 75.00

Total 62 raw suppliers

Chemical Property of Methyl 2-bromo-5-methoxybenzoate

Chemical Property:

Vapor Pressure:0.00189mmHg at 25°C
Refractive Index:n20/D 1.563
Boiling Point:291.9 °C at 760 mmHg
Flash Point:130.4 °C
PSA：35.53000
Density:1.463 g/cm³
LogP:2.24430
Storage Temp.:Sealed in dry,Room Temperature
Water Solubility.:Not miscible in water.
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:243.97351
Heavy Atom Count:13
Complexity:184

Purity/Quality:

99%, ^*data from raw suppliers

Methyl 2-Bromo-5-methoxybenzoate ^*data from reagent suppliers

Safty Information:

Pictogram(s): T
Hazard Codes:T
Statements: 25
Safety Statements: 45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC1=CC(=C(C=C1)Br)C(=O)OC
Uses Methyl 2-bromo-5-methoxybenzoate is used as pharmaceutical intermediate.

Technology Process of Methyl 2-bromo-5-methoxybenzoate

There total 10 articles about Methyl 2-bromo-5-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 67-56-1
methanol

: 22921-68-2
2-bromo-5-methoxy-benzoic acid

: 35450-36-3
methyl 2-bromo-5-methoxybenzoate

Guidance literature:: With thionyl chloride; at 40 ℃; for 18h;
DOI:10.1016/S0040-4020(98)00655-3

Reference yield: 98.0%

: 74-88-4
methyl iodide

: 154607-00-8
methyl 3-hydroxy-6-bromobenzoate

: 35450-36-3
methyl 2-bromo-5-methoxybenzoate

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 18h; Inert atmosphere;
DOI:10.1039/d1ob01827b

Reference yield: 95.0%

: 5368-81-0
methyl 3-methoxybenzoate

: 35450-36-3
methyl 2-bromo-5-methoxybenzoate

Guidance literature:: With N-Bromosuccinimide; diphenyldisulfane; In acetonitrile; at 20 ℃; for 6.5h; Reagent/catalyst;
DOI:10.1021/acs.joc.9b00817