2-azanidylethylazanide; palladium(+2) cation; tetrachloropalladium

Base Information

• Chemical Name: 2-azanidylethylazanide; palladium(+2) cation; tetrachloropalladium
• CAS No.: 14099-33-3
• Molecular Formula: C4H12Cl4N4Pd2-2
• Molecular Weight: 470.818
• Mol file: 14099-33-3.mol

Synonyms:

Chemical Property of 2-azanidylethylazanide; palladium(+2) cation; tetrachloropalladium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-azanidylethylazanide; palladium(+2) cation; tetrachloropalladium

There total 1 articles about 2-azanidylethylazanide; palladium(+2) cation; tetrachloropalladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium tetrachloropalladate(II) (10025-98-6) → cis-dichloro(ethylenediamine)palladium(II) (15020-99-2) + bis-(ethylendiamine)palladium(II) tetrachloropalladate (II) (14099-33-3)

Guidance literature:

With (CH₂NH₂)2; In water; H.D.K. Drew, H.J. Tress, J. Chem. Soc., 1935,1244; F. Basolo, J.C. Bailar, jun., B.R. Tarr, J.Am.Chem.Soc., 1950,72,2433; F. Basolo, H.B. Gray, R.B. Pearson, J.Am.Chem.Soc., 1960, 82,4200;aq. soln. of amine added dropwise to stirred aq. soln. of K2PdCl4; filtered immediately, futher amine added, procedure repeated until no more Pd(en)Cl2 pptd., washed (cold H2O, abs.EtOH, Et2O), dried in air; by keeping low concn. of amine and filtering of Pd(en)Cl2 the yield of pink Pd(en)2)(PdCl4) was kept to min.;;

DOI:10.1039/DT9850000815

Reference yield:

bis-(ethylendiamine)palladium(II) tetrachloropalladate (II) (14099-33-3) + ethylenediamine (107-15-3,85404-18-8) → bis(ethylenediamine)palladium(II) chloride (16483-18-4)

Guidance literature:

In not given; on react. of excess ethylenediamine with soln. of (Pd(C2H4(NH2)2)(PdCl4);;

Reference yield:

bis-(ethylendiamine)palladium(II) tetrachloropalladate (II) (14099-33-3) + ammonia (7664-41-7) → tetramminepalladium(II) chloride (13815-17-3)

Guidance literature:

upstream raw materials:

potassium tetrachloropalladate(II)

Downstream raw materials:

cis-dichloro(ethylenediamine)palladium(II)

tetramminepalladium(II) chloride

bis(ethylenediamine)palladium(II) chloride

Refernces