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13815-17-3

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13815-17-3 Usage

Flammability and Explosibility

Nonflammable

Check Digit Verification of cas no

The CAS Registry Mumber 13815-17-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,1 and 5 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13815-17:
(7*1)+(6*3)+(5*8)+(4*1)+(3*5)+(2*1)+(1*7)=93
93 % 10 = 3
So 13815-17-3 is a valid CAS Registry Number.
InChI:InChI=1/2ClH.4H2N.Pd/h2*1H;4*1H2;/q;;4*-1;+2/p-2

13815-17-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name Tetraamminepalladium(II) dichloride

1.2 Other means of identification

Product number -
Other names Tetramminepalladium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13815-17-3 SDS

13815-17-3Downstream Products

13815-17-3Relevant articles and documents

Propylene epoxidation with hydrogen peroxide over palladium containing titanium silicalite

Laufer,Meiers,Hoelderich

, p. 215 - 221 (1999)

The epoxidation of propylene to propylene oxide with H2O2 was studied over palladium impregnated and reduced titanium silicalite (TS-1), over merely impregnated titanium tilicalite and over untreated titanium silicalite. The use of such catalytic systems in the epoxidation of propylene with a H2-O2 mixture motivated us to assess the influence of operating conditions and the effect of the Pd loading on the epoxidation capability of the titanium silicalite catalyst. Concerning the operating conditions TS-1 was found to be very active even at temperatures as low as 10°C. Lowering the H2O2 concentrations to only 2 wt.% of H2O2 caused the PO yield to increase slightly over TS-1 and 1% Pd/TS-1. TS-1 catalysts that were merely impregnated with [Pd(NH3)4]Cl2 were less active than the catalysts that were reduced after impregnation, though the latter is more active in the decomposition of H2O2. The deactivation of TS-1 after impregnation with [Pd(NH3)4]Cl2 was probably caused by the blocking of the Ti sites by ammonia, since the impregnation with PdCl2 did not cause any decrease in activity. Reducing the catalyst removes the ammonia and improves the catalytic performance of the Pd loaded catalyst.

Solid-State Thermal Transformations in a Mixture of Palladium Tetraammine Dichloride with Ammonium Chromate

Fesik,Buslaeva,Mel’nikova,Tarasova

, p. 1299 - 1307 (2018)

Abstract—: Solid-state transformations of a 3[Pd(NH3)4]Cl2 + (NH4)2CrO4 mixture at temperatures from 40?to 550°C in various media have been studied by thermal analysis and mass spectrometry. The results demonstrate that the solid thermolysis product obtained in an argon atmosphere consists of a single phase: palladium-based Pd1?–?xCrx solid solution isostructural with palladium and having a unit-cell parameter a = 3.897(2) ?. Its formation proceeds through the formation of metallic Pd and Cr, as evidenced by the absence of chromium oxide phases in all of the solid intermediate thermolysis products. The solid thermolysis product obtained in air consists of the phases Pd and PdO. A model has been proposed for the transformations of the 3[Pd(NH3)4]Cl2 + (NH4)2CrO4 mixture through the formation of metallic palladium and chromium.

Gallic acid-assisted synthesis of Pd uniformly anchored on porous N-rGO as efficient electrocatalyst for microbial fuel cells

Wu, Xiao-Tong,Li, Jie-Cheng,Pan, Qiu-Ren,Li, Nan,Liu, Zhao-Qing

, p. 1442 - 1450 (2018)

The sluggish kinetic rate-limiting oxygen reduction reaction (ORR) at the cathode remains the foremost issue hindering the commercialization of microbial fuel cells (MFCs). Utilization of the effect of micromolecule conjugation and the synergistic effect between Pd nanoparticles and N-rGO (nitrogen-doped reduced graphene oxide) to stabilize a precious metal onto carbon materials is a promising strategy to design and synthesize highly efficient cathode catalysts. In this study, gallic acid is used to facilitate the coupling of palladium (Pd) with N-rGO to form GN@Pd-GA via a simple hydrothermal process. Notably, the as-synthesized GN@Pd-GA as a cathode catalyst shows an approximately direct four-electron feature and demonstrates a high ORR performance in 0.1 M KOH. Furthermore, the stability and methanol tolerance of GN@Pd-GA are superior to those of the commercial Pt/C catalysts. In addition, a maximum power density of 391.06 ± 0.2 mW m-2 of MFCs equipped with GN@Pd-GA was obtained, which was 96.2% of the power density of MFCs equipped with a commercial Pt/C catalyst.

Synthesis of ruthenium(iii) and rhodium(iii) tris-acetylacetonates and palladium(ii) bis-ketoiminate using microwave heating

Chimitov,Zherikova,Mikheev,Zharkova,Morozova,Igumenov,Arzhannikov,Tumm

, p. 2236 - 2242 (2012)

Preparation of ruthenium(iii) and rhodium(iii) tris-acetylacetonates and palladium(ii) bisketoiminate (Pd(i-acac)2) under microwave irradiation using different synthetic conditions, both in the solid-phase and in solution, was studied with precise control of parameters. In the solid-phase systems, the preparation of the target product was hindered. The efficiency of the microwave heating increased when liquid phases of the reagent mixtures were used. For Pd(i-acac)2, the highest yield was achieved under elevated temperature of the process, with the reaction time decreasing to several minutes. A laboratory procedure for the microwave synthesis of ruthenium(iii) and rhodium(iii) tris-acetylacetonates and palladium(ii) bis-ketoiminate in aqueous solutions was developed, which allowed us to obtain them in 85, 55, and 80% yields, respectively. These yields are higher than those reported in the literature, with the process becoming considerably less time consuming and laborious.

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