Stannane, (3-chloro-1-propynyl)triphenyl-

Base Information

Chemical Name:Stannane, (3-chloro-1-propynyl)triphenyl-
CAS No.:92752-97-1
Molecular Formula:C21H17ClSn
Molecular Weight:423.529
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Stannane, (3-chloro-1-propynyl)triphenyl-

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Technology Process of Stannane, (3-chloro-1-propynyl)triphenyl-

There total 1 articles about Stannane, (3-chloro-1-propynyl)triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 624-65-7
2-propynyl chloride

: 639-58-7
triphenyltin chloride

: 92752-97-1
(C₆H₅)3SnCCCH₂Cl

Guidance literature:: 2-propynyl chloride; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;

triphenyltin chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 18.5h; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1039/c5dt03558a

Reference yield:

: 109-72-8,29786-93-4
n-butyllithium

: 92752-97-1
(C₆H₅)3SnCCCH₂Cl

: 829-85-6
diphenylphosphane

: C₃₃H₂₇PSn

: 2847-57-6
butyltriphenyltin

Guidance literature:: n-butyllithium; diphenylphosphane; In diethyl ether; at -78 ℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;

(C₆H₅)3SnCCCH₂Cl; In diethyl ether; at -78 - 20 ℃; for 18.5h; Overall yield = 0.8 g; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1039/c5dt03558a

Reference yield:

: 92752-97-1
(C₆H₅)3SnCCCH₂Cl

: 18365-12-3
n-Propylkupfer(I)

: 92753-01-0
(C₆H₅)3SnC(CH₂CH₂CH₃)CCH₂

Guidance literature:: In tetrahydrofuran; propargylic chloride was added under N2 at -60°C to a soln. of n-PrCu in THF, mixt. was stirred for 1 h at -60°C; the product probably was contaminated with ca. 10% of n-PrSnPh3; mixt. was poured into satd. aq. NH4Cl containing NaCN, extd. with 1:1 ether-pentane, combined exts. were washed with water, dried over MgSO4, solvent was evapd. in vacuo, residue crystd. from methanol or purified by column chromy. (Al2O3, hexane);
DOI:10.1016/0022-328X(84)80703-2