Platinum(II)iodide

Base Information

• Chemical Name: Platinum(II)iodide
• CAS No.: 7790-39-8
• Molecular Formula: I₂Pt
• Molecular Weight: 448.889
• Wikidata: Q4202661
• Mol file: 7790-39-8.mol

Synonyms:Platinum(II)iodide;Platinum(II) iodide, Premion, 99.99% (metals basis), Pt 43.0% min;MFCD00011183;PLATINUM IODIDE, PtI2;Platinum(II) iodide, 98%;Platinum(II) iodide, Premion?;Platinum(II) iodide, min. 98%;CS-0111332;Q4202661

Chemical Property of Platinum(II)iodide

Chemical Property:

• Vapor Pressure: 13.8mmHg at 25°C
• Melting Point: 360 °C (dec.)(lit.)
• Boiling Point: 127ºC at 760 mmHg
• PSA: 0.00000
• Density: 6.4
• LogP: 1.76890
• Water Solubility.: Insoluble in water, alkali iodides.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 448.77374
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Platinum(II) iodide, min. 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:Irritating to eyes, respiratory system and skin.; R43:May cause sensitization by skin contact.
• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: I[Pt]I
• Uses: Platinum(II) iodide is used in pharmaceuticals and medical applications. It is also used to form cis and trans complexes with propan-1-amine. It is utilized in the catalytic hydration reaction of alkynes such as 2-hexyne, 4-methyl-2-pentyne, and 4,4dimethyl-2- pentyne . It is also used in the preparation of diiodo(2,9-dimethyl-1,10-phenanthroline)platinum(II).

Technology Process of Platinum(II)iodide

There total 35 articles about Platinum(II)iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

potassium tetrachloroplatinate(II) (10025-99-7) + 1-methyluracil (615-77-0) → trans-K2{PtI2(1-methyluracil)2}*6H2O + platinum(II) iodide (7790-39-8)

Guidance literature:

With KI; KOH; In water; addn. of KOH soln. to uracil; addn. of KI soln. to K2PtCl4 soln.; slow addn. of KOH/uracil soln.; pptn. of PtI2; standing, 30°C, 1d; filtration; very slow evapn. of filtrate, 30°C; crystn. within several weeks; elem. anal.;

DOI:10.1016/0020-1693(93)03794-B

Reference yield:

[PtL2] + potassium iodide (7681-11-0) → methyl red (493-52-7) + platinum(II) iodide (7790-39-8)

Guidance literature:

In water; water bath (4 h); ppt. filtration off, washing (water), drying (70°C); elem. anal.;

Reference yield:

tetraiodo-dicarbonyl-diplatinum(II) → platinum (7440-06-4) + platinum(II) iodide (7790-39-8)

Guidance literature:

In ethanol; heating the alc. soln.;;

upstream raw materials:

iodine

platinum

potassium tetrachloroplatinate(II)

methyl iodide

Downstream raw materials:

{(C₆F₅)3P}2PtI₂

{Pt2}

trans-[PtI₂(4-(3,5-diisopropyl-4-isocyanophenyl)ethynyl-1-ethynylbenzene)2]

trans-[PtI₂(2,6-diisopropyl-4-iodo-1-isocyanobenzene)2]

Refernces

• 1、 Renn, Oliver,Lippert, Bernhard,Mutikainen, Ilpo. "". . p. 117 - 120. Retrieved 1994.
• 2、 Kukushkin,Pakhomova. "Platinum Iodide Compounds". . p. 69 - 70. Retrieved 2008/10/08.