2-methyltricyclo[3.3.1.1~3,7~]decane

Base Information

• Chemical Name: 2-methyltricyclo[3.3.1.1~3,7~]decane
• CAS No.: 700-75-4
• Molecular Formula: C9H13 N O
• Molecular Weight: 151.208
• Mol file: 700-75-4.mol

Synonyms:o-Anisidine,N,N-dimethyl- (6CI,7CI,8CI); 2-Methoxy-N,N-dimethylbenzenamine;N,N-Dimethyl-o-anisidine; N,N-Dimethyl-o-methoxyaniline;o-(Dimethylamino)anisole; o-Methoxy-N,N-dimethylaniline

Chemical Property of 2-methyltricyclo[3.3.1.1~3,7~]decane

Chemical Property:

• Boiling Point: 200.2°Cat760mmHg
• Flash Point: 59.2°C
• Density: 0.942g/cm³

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-methyltricyclo[3.3.1.1~3,7~]decane

There total 26 articles about 2-methyltricyclo[3.3.1.1~3,7~]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methanol (67-56-1) + 2-methoxy-phenylamine (90-04-0) → 2-methoxy-N,N-dimethyl-benzenamine (700-75-4)

Guidance literature:

With tetrachloromethane; copper(ll) bromide; at 180 ℃; for 6h; Inert atmosphere; Sealed tube;

DOI:10.1134/S1070428018110052

Reference yield: 93.0%

2-methoxy-N,N-dimethylanilineN-oxide → 2-methoxy-N,N-dimethyl-benzenamine (700-75-4)

Guidance literature:

With phenylboronic acid; In dichloromethane; at 20 ℃; for 0.333333h;

DOI:10.1016/j.tetlet.2017.01.051

Reference yield: 93.0%

4-iodoanisol (529-28-2) + dimethyl amine (124-40-3) → 2-methoxy-N,N-dimethyl-benzenamine (700-75-4)

Guidance literature:

With copper(l) iodide; 6,7-dihydro-5H-quinolin-8-one oxime; potassium hydroxide; In water; at 65 ℃; for 24h; Inert atmosphere;

DOI:10.1002/adsc.201400785

upstream raw materials:

2-methoxy-phenylamine

dimethyl sulfate

2-(trimethylammonio)phenolate

tri-N-methyl-o-anisidinium; iodide

Downstream raw materials:

N-(2-methoxyphenyl)-N-methylnitrous amide

2-methoxy-N-methyl-4-nitro-N-nitroso-aniline

2-methoxy-N,N-dimethyl-4-nitroaniline

N,N-dimethyl-2-methoxy-5-nitroaniline