Dichlorovinylsilane

Base Information

• Chemical Name: Dichlorovinylsilane
• CAS No.: 18076-99-8
• Molecular Formula: C2H3Cl2Si
• Molecular Weight: 127.045
• Hs Code.: 2931900090
• European Community (EC) Number: 241-984-3
• DSSTox Substance ID: DTXSID30939379
• Wikidata: Q82915849
• Mol file: 18076-99-8.mol

Synonyms:vinyldichlorosilane

Chemical Property of Dichlorovinylsilane

Chemical Property:

• Boiling Point: 65.2°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.40970
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 124.9381070
• Heavy Atom Count: 5
• Complexity: 34.6

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C[Si](Cl)Cl

Technology Process of Dichlorovinylsilane

There total 12 articles about Dichlorovinylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis(diethylamino)vinylsilane → dichlorovinylsilane (18076-99-8)

Guidance literature:

With Dichlorophenylphosphine; In tetralin; for 4h; Ambient temperature;

DOI:10.1016/0022-328X(89)88036-2

Reference yield: 61.5%

trichlorovinylsilane (75-94-5) → dichlorovinylsilane (18076-99-8)

Guidance literature:

With tributyl-amine; phenylsilane;

DOI:10.1007/BF02494818

Reference yield: 36.0%

vinylsilane (7291-09-0) → dichlorovinylsilane (18076-99-8) + vinyl chlorosilane (1504-89-8)

Guidance literature:

With hydrogenchloride; In diethylene glycol dimethyl ether; at 60 ℃; for 13.33h;

upstream raw materials:

chloroethylene

acetylene

triethenylsilane

trichlorovinylsilane

Downstream raw materials:

chloro-trimethyl-silane

Refernces

• 1、 Guirgis, Gamil A.,Zhen, Pengqian,Durig, James R.. "Spectra and structure of silicon containing compounds. XXVII. Raman and infrared spectra, conformational stability, vibrational assignment and ab initio calculations of vinyldichlorosilane". . . Retrieved 2000.
• 2、 -. "SYNTHESIS OF ORGANO CHLOROSILANES FROM ORGANOSILANES". Page/Page column 36; 37; 38. . Retrieved 2019/04/16.