Methyl 2-Bromo-4-methoxybenzoate

Base Information

Chemical Name:Methyl 2-Bromo-4-methoxybenzoate
CAS No.:17100-65-1
Molecular Formula:C9H9BrO3
Molecular Weight:245.073
Hs Code.:2918990090
European Community (EC) Number:800-618-8
DSSTox Substance ID:DTXSID70568369
Nikkaji Number:J2.458.222A
Wikidata:Q82454603
Mol file:17100-65-1.mol

Synonyms:Methyl 2-Bromo-4-methoxybenzoate;17100-65-1;METHYL2-BROMO-4-METHOXYBENZOATE;MFCD12026001;SCHEMBL2305885;DTXSID70568369;MGIYCRUAYQQSNL-UHFFFAOYSA-N;methyl 2-bromo-4-methoxy-benzoate;5-Chloro-2-FluorophenylboronicAcid;CL9443;AKOS015834900;CS-W022802;FS-2233;AC-28546;SY101881;A881964;J-521959

Suppliers and Price of Methyl 2-Bromo-4-methoxybenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
Methyl 2-bromo-4-methoxybenzoate
5g
$ 318.00

Matrix Scientific
Methyl 2-bromo-4-methoxybenzoate
1g
$ 79.00

Crysdot
Methyl2-bromo-4-methoxybenzoate 98%
5g
$ 133.00

Crysdot
Methyl2-bromo-4-methoxybenzoate 98%
1g
$ 44.00

Crysdot
Methyl2-bromo-4-methoxybenzoate 98%
10g
$ 220.00

Chemenu
Methyl2-bromo-4-methoxybenzoate 95+%
25g
$ 926.00

Chemenu
Methyl2-bromo-4-methoxybenzoate 95+%
5g
$ 309.00

Chemenu
Methyl2-bromo-4-methoxybenzoate 95+%
10g
$ 477.00

Chemcia Scientific
2-Bromo-4-methoxy-benzoicacidmethylester ＞97%
10 G
$ 450.00

Chemcia Scientific
2-Bromo-4-methoxy-benzoicacidmethylester ＞97%
5 G
$ 260.00

Total 17 raw suppliers

Chemical Property of Methyl 2-Bromo-4-methoxybenzoate

Chemical Property:

Vapor Pressure:0.002mmHg at 25°C
Melting Point:29 °C
Boiling Point:292.939°C at 760 mmHg
Flash Point:130.965°C
PSA：35.53000
Density:1.463g/cm³
LogP:2.24430
Storage Temp.:Sealed in dry,Room Temperature
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:243.97351
Heavy Atom Count:13
Complexity:184

Purity/Quality:

97% ^*data from raw suppliers

Methyl 2-bromo-4-methoxybenzoate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=CC(=C(C=C1)C(=O)OC)Br

Technology Process of Methyl 2-Bromo-4-methoxybenzoate

There total 8 articles about Methyl 2-Bromo-4-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 67-56-1
methanol

: 74317-85-4
2-bromo-4-methoxybenzoic acid

: 17100-65-1
2-bromo-4-methoxybenzoic acid methyl ester

Guidance literature:: With sulfuric acid; In water; at 80 ℃; for 5h;

Reference yield: 95.9%

: 101085-03-4
2-bromo-4-hydroxybenzoic acid methyl ester

: 74-88-4
methyl iodide

: 17100-65-1
2-bromo-4-methoxybenzoic acid methyl ester

Guidance literature:: 2-bromo-4-hydroxybenzoic acid methyl ester; With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 0.333333h; Inert atmosphere;

methyl iodide; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2h; Inert atmosphere;
DOI:10.1021/ol401197n

Reference yield:

: 98545-64-3
methyl-2-bromo-4-aminobenzoate

: 17100-65-1
2-bromo-4-methoxybenzoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: sulfuric acid / water / 5 h / 90 °C / Inert atmosphere

1.2: 0 - 20 °C / Inert atmosphere

1.3: 1 h / 90 °C / Inert atmosphere

2.1: potassium carbonate / N,N-dimethyl-formamide / 0.33 h / 20 °C / Inert atmosphere

2.2: 2 h / 0 - 20 °C / Inert atmosphere

With sulfuric acid; potassium carbonate; In water; N,N-dimethyl-formamide;
DOI:10.1021/ol401197n