methyl 4-bromo-3-methylthiophene-2-carboxylate

Base Information

Chemical Name:methyl 4-bromo-3-methylthiophene-2-carboxylate
CAS No.:265652-38-8
Molecular Formula:C7H7BrO2S
Molecular Weight:235.1
Hs Code.:
Mol file:265652-38-8.mol

Synonyms:methyl 4-bromo-3-methylthiophene-2-carboxylate;4-bromo-3-methyl-2-Thiophenecarboxylic acid methyl ester

Suppliers and Price of methyl 4-bromo-3-methylthiophene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Methyl4-bromo-3-methylthiophene-2-carboxylate 95+%
100g
$ 2351.00

Crysdot
Methyl4-bromo-3-methylthiophene-2-carboxylate 95+%
10g
$ 429.00

Crysdot
Methyl4-bromo-3-methylthiophene-2-carboxylate 95+%
25g
$ 808.00

Chemenu
Methyl4-bromo-3-methylthiophene-2-carboxylate 95%
25g
$ 755.00

Chemenu
Methyl4-bromo-3-methylthiophene-2-carboxylate 95%
10g
$ 401.00

Chemcia Scientific
4-Bromo-3-methyl-thiophene-2-carboxylicacidmethylester 95%
5 G
$ 270.00

Alichem
Methyl4-bromo-3-methylthiophene-2-carboxylate
100g
$ 2327.49

Alichem
Methyl4-bromo-3-methylthiophene-2-carboxylate
10g
$ 437.58

Total 7 raw suppliers

Chemical Property of methyl 4-bromo-3-methylthiophene-2-carboxylate

Chemical Property:

Melting Point:61-61.5 °C
Boiling Point:263.3±35.0 °C(Predicted)
PSA：54.54000
Density:1.575±0.06 g/cm3(Predicted)
LogP:2.60560
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Methyl4-bromo-3-methylthiophene-2-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 4-bromo-3-methylthiophene-2-carboxylate

There total 7 articles about methyl 4-bromo-3-methylthiophene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 81452-54-2
methyl 3-methylthiophene-2-carboxylate

: 265652-38-8
methyl 4-bromo-3-methylthiophene-2-carboxylate

Guidance literature:: methyl 3-methylthiophene-2-carboxylate; With bromine; acetic acid; sodium hydroxide; at 60 - 85 ℃; for 6h;

With zinc; In acetic acid; at 85 ℃; for 1h;

Reference yield:

: 265652-39-9
3-methyl-4-bromo-2-thiophenecarboxylic acid

: 18107-18-1
diazomethyl-trimethyl-silane

: 265652-38-8
methyl 4-bromo-3-methylthiophene-2-carboxylate

Guidance literature:: 3-methyl-4-bromo-2-thiophenecarboxylic acid; diazomethyl-trimethyl-silane; In tetrahydrofuran; methanol; diethyl ether; ethyl acetate; at 20 ℃; for 0.5h;

With acetic acid; In tetrahydrofuran; methanol; diethyl ether;

Reference yield:

: 863906-40-5
methyl 4-bromo-3-([(trifluoromethyl)sulfonyl]oxy)-2-thiophenecarboxylate

: 13061-96-6
dihydroxy-methyl-borane

: 265652-38-8
methyl 4-bromo-3-methylthiophene-2-carboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In 1,4-dioxane; water; at 70 ℃; Sealed tube;
DOI:10.1021/acs.jmedchem.1c01437