Ethyltrimethylammonium chloride

Base Information

• Chemical Name: Ethyltrimethylammonium chloride
• CAS No.: 27697-51-4
• Molecular Formula: C5H14 N . Cl
• Molecular Weight: 123.626
• Hs Code.: 2923900090
• European Community (EC) Number: 608-133-1
• DSSTox Substance ID: DTXSID40885398
• Mol file: 27697-51-4.mol

Synonyms:ethyltrimethylammonium;TMEA chloride;trimethylethylammonium;trimethylethylammonium acetate;trimethylethylammonium bromide;trimethylethylammonium chloride;trimethylethylammonium hydroxide;trimethylethylammonium iodide;trimethylethylammonium sulfite (1:1)

Chemical Property of Ethyltrimethylammonium chloride

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -2.28350
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 123.0814771
• Heavy Atom Count: 7
• Complexity: 33.7

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[N+](C)(C)C.[Cl-]

Technology Process of Ethyltrimethylammonium chloride

There total 3 articles about Ethyltrimethylammonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

N,N-dimethyl-ethanamine (598-56-1) + methyl chloroformate (79-22-1) → ethyltrimethylammonium chloride (27697-51-4)

Guidance literature:

In dichloromethane; at 20 ℃; for 9h; Cooling with ice; Heating; Schlenk technique;

DOI:10.1021/jacs.8b10638

Reference yield: 42.9%

trimethylamine hydrochloride (593-81-7) + Diethyl carbonate (105-58-8,76619-83-5) → ethyltrimethylammonium chloride (27697-51-4)

Guidance literature:

With 1-ethyl-3-methylimidazolium bromide; at 169.84 ℃; for 8h;

DOI:10.1002/adsc.200600451

Reference yield:

chloroethane (75-00-3) + trimethylamine (75-50-3) → ethyltrimethylammonium chloride (27697-51-4)

Guidance literature:

With ethanol; im Einschmelzrohr;

upstream raw materials:

chloroethane

trimethylamine

trimethylamine hydrochloride

Diethyl carbonate

Downstream raw materials:

methylene chloride

N,N-dimethyl-ethanamine

chloroethane

trimethylamine

Refernces

• 1、 Sun, Dong-Sheng,Zhang, Yao-Zu,Gao, Ji-Xing,Hua, Xiu-Ni,Chen, Xiao-Gang,Mei, Guang-Quan,Liao, Wei-Qiang. "Reversible high temperature dielectric switching in a 2H-perovskite compound: [Me3NCH2CH3]CdCl3". . p. 2669 - 2674. Retrieved 2019/04/25.
• 2、 Zheng, Zhuo Qun,Wang, Jie,Wu, Ting Hua,Zhou, Xiao Ping. "Alkylation of ammonium salts catalyzed by imidazolium-based ionic liquid catalysts". . p. 1095 - 1101. Retrieved 2008/03/27.