2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole

Base Information

Chemical Name:2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole
CAS No.:438568-89-9
Molecular Formula:C₇H₈BrNS
Molecular Weight:218.117
Hs Code.:2934200090
DSSTox Substance ID:DTXSID30431848
Mol file:438568-89-9.mol

Synonyms:2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole;438568-89-9;2-bromo-4,5,6,7-tetrahydro-1,3-benzothiazole;2-Bromo-4,5,6,7-tetrahydro-benzothiazole;2-bromo-4,5,6,7-tetrahydrobenzothiazole;SCHEMBL3090628;DTXSID30431848;ZOKVOUATOUMFEK-UHFFFAOYSA-N;MFCD13195374;AKOS015994841;DS-11970;CS-0038757;EN300-841384;F19594;A872631;F2167-0086

Suppliers and Price of 2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Bromo-4,5,6,7-tetrahydro-benzothiazole
100mg
$ 130.00

Crysdot
2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole 95+%
1g
$ 325.00

Crysdot
2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole 95+%
100mg
$ 81.00

Crysdot
2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole 95+%
250mg
$ 130.00

Chemenu
2-bromo-4,5,6,7-tetrahydrobenzo[d]thiazole 95%
1g
$ 307.00

Chemcia Scientific
2-Bromo-4,5,6,7-tetrahydro-benzothiazole 95%
5 G
$ 875.00

American Custom Chemicals Corporation
2-BROMO-4,5,6,7-TETRAHYDROBENZO[D]THIAZOLE 95.00%
250MG
$ 320.25

Alichem
2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole
1g
$ 334.56

AK Scientific
2-Bromo-4,5,6,7-tetrahydro-benzothiazole
1g
$ 696.80

Total 10 raw suppliers

Chemical Property of 2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole

Chemical Property:

Boiling Point:284.9±9.0 °C(Predicted)
PKA:1.95±0.20(Predicted)
PSA：41.13000
Density:1.613±0.06 g/cm3(Predicted)
LogP:2.78440
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:216.95608
Heavy Atom Count:10
Complexity:131

Purity/Quality:

97% ^*data from raw suppliers

2-Bromo-4,5,6,7-tetrahydro-benzothiazole ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC2=C(C1)N=C(S2)Br

Technology Process of 2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole

There total 6 articles about 2-Bromo-4,5,6,7-tetrahydrobenzo[d]thiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.8%

: 2933-29-1
2-Amino-4,5,6,7-tetrahydrobenzothiazole

: 438568-89-9
2-bromo-4,5,6,7-tetrahydrobenzo[d]thiazole

Guidance literature:: With tert.-butylnitrite; copper(ll) bromide; In acetonitrile; at 40 ℃; for 2h;

Reference yield:

: 144-55-8
sodium hydrogencarbonate

: 23839-33-0
2-thiocyanatocyclohexanone

: 438568-89-9
2-bromo-4,5,6,7-tetrahydrobenzo[d]thiazole

Guidance literature:: In dichloromethane; hydrogen bromide;

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 438568-89-9
2-bromo-4,5,6,7-tetrahydrobenzo[d]thiazole

Guidance literature:: Multi-step reaction with 3 steps

1: N-Bromosuccinimide; toluene-4-sulfonic acid / dichloromethane; cyclohexanone / 4 h / 0 °C / Reflux

2: ethanol / 4 h / Reflux

3: copper(ll) bromide; tert.-butylnitrite / acetonitrile / 2 h / 40 °C

With N-Bromosuccinimide; tert.-butylnitrite; toluene-4-sulfonic acid; copper(ll) bromide; In ethanol; dichloromethane; cyclohexanone; acetonitrile;