cis-alpha-Nitrostilbene

Base Information

• Chemical Name: cis-alpha-Nitrostilbene
• CAS No.: 4714-25-4
• Molecular Formula: C14H11NO2
• Molecular Weight: 225.247
• Nikkaji Number: J496.402K
• NSC Number: 52231
• Mol file: 4714-25-4.mol

Synonyms:cis-alpha-nitrostilbene;SCHEMBL5442818;4714-25-4;NSC52231;NSC-52231

Chemical Property of cis-alpha-Nitrostilbene

Chemical Property:

• Vapor Pressure: 2.38E-05mmHg at 25°C
• Boiling Point: 370.3°Cat760mmHg
• Flash Point: 173.1°C
• Density: 1.22g/cm³
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 225.078978594
• Heavy Atom Count: 17
• Complexity: 276

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=CC2=CC=CC=C2[N+](=O)[O-]
• Isomeric SMILES: C1=CC=C(C=C1)/C=C\C2=CC=CC=C2[N+](=O)[O-]

Technology Process of cis-alpha-Nitrostilbene

There total 39 articles about cis-alpha-Nitrostilbene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzyltriphenylphosphonium bromide (1449-46-3) + 2-nitro-benzaldehyde (552-89-6) → 2-nitrostilbene (4714-25-4)

Guidance literature:

With 18-crown-6 ether; potassium carbonate; In dichloromethane; for 6h; Reflux;

DOI:10.1002/cmdc.201600305

Reference yield: 100.0%

(2-nitrobenzyl)triphenylphosphonium bromide (23308-83-0) + benzaldehyde (100-52-7) → 2-nitrostilbene (4714-25-4)

Guidance literature:

(2-nitrobenzyl)triphenylphosphonium bromide; With potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 2h;

benzaldehyde; In dimethyl sulfoxide; at 20 ℃; for 18h;

DOI:10.1021/jo200320k

Reference yield: 99.0%

1-ethylsulfanyl-2-nitrobenzene (3058-46-6) + trans-2-phenylvinylboronic acid (6783-05-7) → 2-nitrostilbene (4714-25-4)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; In methanol; at 22 ℃; for 2h; chemoselective reaction;

DOI:10.1039/c3sc50773d

upstream raw materials:

piperidine

2-(2-nitro-phenyl)-3-phenyl-acrylic acid

tetrachloromethane

2-(2-nitrophenyl)acetic acid

Downstream raw materials:

2-(2-phenylethenyl)benzenamine

(E)-2-nitrostilbene

2-(2-phenylethyl)aniline

2-phenyl-indole