1-Propene, 3,3'-[(1-methylethylidene)bis(oxy)]bis-

Base Information

• Chemical Name: 1-Propene, 3,3'-[(1-methylethylidene)bis(oxy)]bis-
• CAS No.: 35219-73-9
• Molecular Formula: C9H16O2
• Molecular Weight: 156.225
• Hs Code.: 2909199090
• European Community (EC) Number: 252-445-7
• DSSTox Substance ID: DTXSID7067900
• Nikkaji Number: J289.939F
• Wikidata: Q81994567
• Mol file: 35219-73-9.mol

Synonyms:2,2-bis(prop-2-enoxy)propane;35219-73-9;2,2-Diallyloxypropane;1-Propene, 3,3'-[(1-methylethylidene)bis(oxy)]bis-;Propane, 2,2-di(2-propenyloxy);EINECS 252-445-7;1-Propene, 3,3'-((1-methylethylidene)bis(oxy))bis-;3,3'-((1-Methylethylidene)bis(oxy))bispropene;3,3'-[(1-methylethylidene)bis(oxy)]bispropene;Propane, 2,2-diallyloxy;acetone diallyl ketal;SCHEMBL3990347;DTXSID7067900;AKOS006274609;3,3'-[(1-Methylethylidene)bis(oxy)]di(1-propene);3-{[2-(PROP-2-EN-1-YLOXY)PROPAN-2-YL]OXY}PROP-1-ENE

Chemical Property of 1-Propene, 3,3'-[(1-methylethylidene)bis(oxy)]bis-

Chemical Property:

• Boiling Point: 172.841 °C at 760 mmHg
• Flash Point: 37.266 °C
• PSA: 18.46000
• Density: 0.868 g/cm³
• LogP: 2.12770
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 156.115029749
• Heavy Atom Count: 11
• Complexity: 114

Purity/Quality:

98%Min ^*data from raw suppliers

2,2-DIALLYLOXYPROPANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(OCC=C)OCC=C

Technology Process of 1-Propene, 3,3'-[(1-methylethylidene)bis(oxy)]bis-

There total 10 articles about 1-Propene, 3,3'-[(1-methylethylidene)bis(oxy)]bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

allyloxytrimethylsilane (18146-00-4) + acetone (67-64-1) → 2,2-bis-allyloxy-propane (35219-73-9)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -78 ℃; for 3h;

DOI:10.1080/00397919508011393

Reference yield:

allyl alcohol (107-18-6) + prop-1-yne (74-99-7) → 2,2-bis-allyloxy-propane (35219-73-9)

Guidance literature:

With methyl(triphenylphosphine)gold(I); methanesulfonic acid; at 20 - 50 ℃;

DOI:10.1002/(SICI)1521-3773(19980605)37:10<1415::AID-ANIE1415>3.0.CO;2-N

Reference yield:

allyl alcohol (107-18-6) + 2,2-dimethoxy-propane (77-76-9) → 2,2-bis-allyloxy-propane (35219-73-9) + 2-methyl-3-oxa-1,5-hexadiene (7623-25-8)

Guidance literature:

With pyridinium p-toluenesulfonate; at 65 - 70 ℃; for 5h;

DOI:10.1021/ja00297a039

upstream raw materials:

toluene-4-sulfonic acid

allyl alcohol

2,2-diethoxypropane

Isopropenyl acetate

Downstream raw materials:

5-Hexen-2-one

2-methyl-3-oxa-1,5-hexadiene

Refernces

• 1、 Teles, J. Henrique,Brode, Stefan,Chabanas, Mathieu. "Cationic gold(I) complexes: Highly efficient catalysts for the addition of alcohols to alkynes". . p. 1415 - 1418. Retrieved 2007/10/03.