2-chloro-4,4-diMethylcyclohex-1-enecarbaldehyde

Base Information

Chemical Name:2-chloro-4,4-diMethylcyclohex-1-enecarbaldehyde
CAS No.:1228943-80-3
Molecular Formula:C9H13ClO
Molecular Weight:172.655
Hs Code.:2912290090
Mol file:1228943-80-3.mol

Synonyms:2-chloro-4,4-diMethylcyclohex-1-enecarbaldehyde;2-chloro-4,4-dimethyl-1-Cyclohexene-1-carboxaldehyde;2-Chloro-4,4-dimethylcyclohex-1-enecarboxaldehyde

Suppliers and Price of 2-chloro-4,4-diMethylcyclohex-1-enecarbaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
2-Chloro-4,4-dimethylcyclohex-1-enecarbaldehyde 97%
25g
$ 1800.00

Matrix Scientific
2-Chloro-4,4-dimethylcyclohex-1-enecarbaldehyde 97%
10g
$ 1224.00

Ambeed
2-Chloro-4,4-dimethylcyclohex-1-enecarbaldehyde 97%
250mg
$ 78.00

Ambeed
2-Chloro-4,4-dimethylcyclohex-1-enecarbaldehyde 97%
100mg
$ 44.00

Total 18 raw suppliers

Chemical Property of 2-chloro-4,4-diMethylcyclohex-1-enecarbaldehyde

Chemical Property:

Boiling Point:224.0±40.0 °C(Predicted)
PSA：17.07000
Density:1.07±0.1 g/cm3(Predicted)
LogP:2.88830

Purity/Quality:

99.9% ^*data from raw suppliers

2-Chloro-4,4-dimethylcyclohex-1-enecarbaldehyde 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-chloro-4,4-diMethylcyclohex-1-enecarbaldehyde

There total 1 articles about 2-chloro-4,4-diMethylcyclohex-1-enecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.9%

: 2979-19-3
3,3-dimethylcyclohexanone

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 1228943-80-3
2-chloro-4,4-dimethyl-2-oxocyclohexenecarbaldehyde

Guidance literature:: N,N-dimethyl-formamide; With trichlorophosphate; In dichloromethane; at -5 - 20 ℃; for 1h; Reflux;

3,3-dimethylcyclohexanone; In dichloromethane; at 0 ℃; for 6.5h; Reflux;

Reference yield: 93.7%

: 1228943-80-3
2-chloro-4,4-dimethyl-2-oxocyclohexenecarbaldehyde

: 1679-18-1
4-Chlorophenylboronic acid

: 1228837-05-5
4'-chloro-5,5-dimethyl-3,4,5,6-tetrahydro-[1,1'-biphenyl]-2-carbaldehyde

Guidance literature:: 2-chloro-4,4-dimethyl-2-oxocyclohexenecarbaldehyde; With tetrabutylammomium bromide; In acetonitrile; at 20 ℃; for 0.166667h;

With potassium carbonate; In acetonitrile; at 20 ℃; for 0.166667h;

4-Chlorophenylboronic acid; In acetonitrile; at 20 - 30 ℃; for 12h; Inert atmosphere;

Reference yield:

: 1228943-80-3
2-chloro-4,4-dimethyl-2-oxocyclohexenecarbaldehyde

: 1235865-77-6
[2-((1H-pyrrolo [2,3-b]pyridin-5-yl)oxy)-4-(4-((4’-chloro-5,5-dimethyl-3,4,5,6-tetrahydro-[1,1’-biphenyl]-2-yl)methyl)piperazin-1-yl)benzoic acid]

Guidance literature:: Multi-step reaction with 5 steps

1.1: tetrabutylammomium bromide / acetonitrile / 0.08 h / 20 °C

1.2: 0.08 h / 20 °C

1.3: 15 h / 30 - 35 °C / Inert atmosphere

2.1: tetrahydrofuran; toluene / 0.08 h / 20 °C

2.2: 4 h / 25 °C

3.1: hydrogenchloride / water; isopropyl alcohol / 12 h / 65 °C

4.1: potassium phosphate / toluene / 0.5 h

4.2: 16 h / 55 °C / Inert atmosphere

5.1: potassium tert-butylate / water; 2-methyltetrahydrofuran / 55 °C / Inert atmosphere

With hydrogenchloride; potassium phosphate; potassium tert-butylate; tetrabutylammomium bromide; In tetrahydrofuran; 2-methyltetrahydrofuran; water; isopropyl alcohol; toluene; acetonitrile;