Platinum(4+) tetrachloride

Base Information

• Chemical Name: Platinum(4+) tetrachloride
• CAS No.: 13454-96-1
• Molecular Formula: PtCl4
• Molecular Weight: 336.892
• Hs Code.: 28439090
• UNII: W3YUG71TU2
• DSSTox Substance ID: DTXSID601014389
• Nikkaji Number: J43.968A
• Mol file: 13454-96-1.mol

Synonyms:platinum(4+) tetrachloride;DTXSID601014389;AKOS016010302;PLATINUM (IV) CHLORIDE [HSDB];PLATINUM TETRACHLORIDE [WHO-DD];A806795

Chemical Property of Platinum(4+) tetrachloride

Chemical Property:

• Appearance/Colour: brown/red crystals
• Melting Point: 370 °C
• PSA: 0.00000
• Density: 4.303 g/cm³
• LogP: 2.75550
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Solubility.: 587g/l
• Water Solubility.: 587 g/L (25 ºC)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 336.837255
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Platinum(IV) chloride (99.9%-Pt) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 22-34-42/43
• Safety Statements: 26-27-36/37/39-45-24-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Pt+4]
• Uses: Platinum(IV) chloride is used as a catalyst and analytical reagent. Further, it is used in the production of semiconductor epitaxy and in electroplating process. It is involved in the preparation of platinum(II) chloride .

Technology Process of Platinum(4+) tetrachloride

There total 37 articles about Platinum(4+) tetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ platinum(IV) chloride (13454-96-1)

Guidance literature:

Reference yield:

sulfuryl dichloride (7791-25-5) + platinum (7440-06-4) → platinum(IV) chloride (13454-96-1)

Guidance literature:

In neat (no solvent); heating for some days to 150°C;;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + platinum (7440-06-4) → platinum(IV) chloride (13454-96-1)

Guidance literature:

With tris-(2-chloro-ethyl)-amine; In not given; byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;;

DOI:10.1021/ja02205a006

upstream raw materials:

sulfuryl dichloride

platinum

hydrogenchloride

chlorine

Downstream raw materials:

carbon dioxide

platinum

platinum(II) sulfide

hydrogen

Refernces

Activation volumes of substitution reactions on neutral and cationic organometallic platinum(IV) complexes: Definite proof of selective associative activation

10.1021/om0499409

The study investigates the activation volumes of substitution reactions on neutral and cationic organometallic platinum(IV) complexes, providing evidence for selective associative activation. The researchers focused on a series of Pt(IV) sulfide organometallic complexes, examining how the electronegativity of the substitution-inert spectator ligands influences the reaction mechanisms, which can be either associatively or dissociatively activated. The chemicals used in the study included various platinum complexes with different ligands, such as 1FSMe, 1ClSMe, 1BrSMe, 2ClSMe, 2ClSEt, 2ClSBzl, 2ClPPh, 2Clpy, 3FSMe, and 4MePPh, as well as entering ligands like PPh3 and SMe2. These chemicals served to explore the tunable associatively/dissociatively activated mechanisms and to understand the effects of ligand size, electronic properties, and solvent interactions on the activation volumes and reaction pathways. The purpose was to gain insights into the mechanisms of substitution reactions involving platinum complexes, which are relevant to catalytic cycles and C-H bond activation processes.

cis-selective single-cleavage skeletal rearrangement of 1,6-enynes reveals the multifaceted character of the intermediates in metal-catalyzed cycloisomerizations

10.1002/anie.200803269

The research focuses on the cis-selective single-cleavage skeletal rearrangement of 1,6-enynes in metal-catalyzed cycloisomerizations, aiming to reveal the multifaceted character of the intermediates involved in these reactions. The study explores the factors controlling the selectivity in the rearrangement of 1,6-enynes, which can lead to different types of products depending on the catalyst used. The researchers concluded that the cis-selective single-cleavage rearrangement of enynes has revealed an unrecognized aspect of gold intermediates in cycloisomerization and related reactions of enynes, where reactions are generally stereospecific but become non-stereospecific in the presence of strongly electron-donating substituents. The chemicals used in the process include various 1,6-enynes, gold catalysts such as AuCl, AuCl(oTol3P), and cationic AuI catalysts, as well as other metal catalysts like PtCl4, GaCl3, and InCl3.