4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-2,2-dioxide

Base Information

• Chemical Name: 4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-2,2-dioxide
• CAS No.: 83947-07-3
• Molecular Formula: C9H12O2S
• Molecular Weight: 184.259
• DSSTox Substance ID: DTXSID901004125

Synonyms:83947-07-3;SCHEMBL4978446;CXZZLFUSMOZARB-UHFFFAOYSA-N;DTXSID901004125;4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-2,2-dioxide;4,7-Methanobenzo(c)thiophene, 1,3,3a,4,7,7a-hexahydro-, 2,2-dioxide, (3aalpha,4alpha,7alpha,7aalpha)-;3-thiatricyclo[5.2.1.02,6]dec-8-ene 3,3-dioxide;2,3,3a,4,7,7a-Hexahydro-1H-4,7-methano-1lambda~6~-1-benzothiophene-1,1-dione;4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-2,2-dioxide, (3a.alpha.,4.alpha.,7.alpha.,7a.alpha.)-

Chemical Property of 4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-2,2-dioxide

Chemical Property:

• Vapor Pressure: 2.38E-05mmHg at 25°C
• Boiling Point: 370.3°C at 760 mmHg
• Flash Point: 234.3°C
• Density: 1.322g/cm³
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 184.05580079
• Heavy Atom Count: 12
• Complexity: 336

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CS(=O)(=O)C2C1C3CC2C=C3

Technology Process of 4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-2,2-dioxide

There total 12 articles about 4,7-Methanobenzo[c]thiophene, 1,3,3a,4,7,7a-hexahydro-2,2-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

endo-4-thiatricyclo<5.2.1.02,6>dec-8-ene (2434-67-5) → endo-4-thiatricyclo<5.2.1.02,6>dec-8-ene 4,4-dioxide (83947-07-3)

Guidance literature:

With potassium peroxomonosulfate; bromine; In methanol; at -20 ℃; for 15h;

Reference yield: 89.0%

endo-4-thiatricyclo<5.2.1.02,6>dec-8-ene (2434-67-5) → exo-9-oxa-endo-4-thiatricyclo<5.2.1.02,6>decane-4,4-dioxide (95722-43-3) + endo-4-thiatricyclo<5.2.1.02,6>dec-8-ene 4,4-dioxide (83947-07-3)

Guidance literature:

With Oxone; In methanol; water; at -5 ℃; for 6h; Time;

DOI:10.3762/bjoc.11.148

Reference yield: 65.0%

amyl iodide (628-17-1) → (1S,7R)-4-Thia-tricyclo[5.2.1.02,6]dec-8-ene 4,4-dioxide (53292-00-5,83947-07-3,93714-07-9) + (1S,3S,7R)-3-Pentyl-4-thia-tricyclo[5.2.1.02,6]dec-8-ene 4,4-dioxide (83927-51-9)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at -78 ℃;

DOI:10.1016/S0040-4039(00)87591-7

upstream raw materials:

endo-4-thiatricyclo<5.2.1.0^2,6>dec-8-ene

Methanesulfonic acid (1S,2R,3S,4R)-3-methanesulfonyloxymethyl-bicyclo[2.2.1]hept-5-en-2-ylmethyl ester

cyclopenta-1,3-diene

(1R,2S,3R,4S)-bicyclo[2.2.1]hept-5-ene-2,3-dimethanol

Downstream raw materials:

1-((1S,2R,3R,6S,7R)-4,4-Dioxo-4λ⁶-thia-tricyclo[5.2.1.0^2,6]dec-8-en-3-yl)-cyclohexanol

1-((1R,3S,7S)-4,4-Dioxo-4λ⁶-thia-tricyclo[5.2.1.0^2,6]dec-8-en-3-yl)-cyclohexanol

cyclopenta-1,3-diene

buta-1,3-diene

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 83947-07-3 2,3,3a,4,7,7a-hexahydro-4,7-methano-1-benzothiophene 1,1-dioxide

Send

Send

Metric Ton KG G Pound L ML

Send

Send